Elements with three p-electrons....
That would be N, P, As, Sb, and Bi -- elements in group 15
For example, energy diagram showing "empty" orbitals up through the 3p.
.....3p __ __ __
3s __
.....2p __ __ __
2s __
1s __
Energy diagram of phosphorous showing three unpaired electrons in 3p-sublevel
.....3p ↑_ ↑_ ↑_
3s ↑↓
.....2p ↑↓ ↑↓ ↑↓
2s ↑↓
1s ↑↓
According to Hund's rule, the electrons singly occupy the p-orbitals, and all have the same spin.
The answer for the question is C
Answer:
A and C are true , B and D are false
Explanation:
For A)
from the first law of thermodynamics (in differential form)
dU= δQ - δW = δQ - PdV
from the second law
dS ≥ δQ/T
then
dU ≤ T*dS - p*dV
dU - T*dS + p*dV ≤ 0
from the definition of Gibbs free energy
G=H - TS = U+ PV - TS → dG= dU + p*dV + V*dp - T*dS - S*dT
dG - V*dp + S*dT = dU - T*dS + p*dV ≤ 0
dG ≤ V*dp - S*dT
in equilibrium, pressure and temperature remains constant ( dp=0 and dT=0). Thus
dG ≤ 0
ΔG ≤ 0
therefore the gibbs free energy should decrease in an spontaneous process → A reaction with a negative Gibbs standard free energy is thermodynamically spontaneous under standard conditions
For B) Since the standard reduction potential is related with the Gibbs standard free energy through:
ΔG⁰=-n*F*E⁰
then, when ΔG⁰ is negative , E⁰ is positive and therefore a coupled redox reaction with a positive standard reduction potential is thermodynamically spontaneous.
Because each carbon atom can form for chemical bonds to another’s atoms and because the carbon atom is just the right small size to fit in comfortably as parts of very large molecules
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