Answer:
The glass transition occur when the given temperature gets drop below the temperature of the glass transition for the polymers. During the creases of the long range of the given motion, the polymer start changing from the state of hard into the form of brittle.
The range of the glass transition temperature are between the 0 to -150°C. The basic use of the polymer is basically depend upon the main properties of the polymer.
Answer:
Tmax= 46.0 lb-in
Explanation:
Given:
- The diameter of the steel rod BC d1 = 0.25 in
- The diameter of the copper rod AB and CD d2 = 1 in
- Allowable shear stress of steel τ_s = 15ksi
- Allowable shear stress of copper τ_c = 12ksi
Find:
Find the torque T_max
Solution:
- The relation of allowable shear stress is given by:
τ = 16*T / pi*d^3
T = τ*pi*d^3 / 16
- Design Torque T for Copper rod:
T_c = τ_c*pi*d_c^3 / 16
T_c = 12*1000*pi*1^3 / 16
T_c = 2356.2 lb.in
- Design Torque T for Steel rod:
T_s = τ_s*pi*d_s^3 / 16
T_s = 15*1000*pi*0.25^3 / 16
T_s = 46.02 lb.in
- The design torque must conform to the allowable shear stress for both copper and steel. The maximum allowable would be:
T = min ( 2356.2 , 46.02 )
T = 46.02 lb-in
The heat transferred to and the work produced by the steam during this process is 13781.618 kJ/kg
<h3>
How to calcultae the heat?</h3>
The Net Change in Enthalpy will be:
= m ( h2 - h1 ) = 11.216 ( 1755.405 - 566.78 ) = 13331.618 kJ/kg
Work Done (Area Under PV curve) = 1/2 x (P1 + P2) x ( V1 - V2)
= 1/2 x ( 75 + 225) x (5 - 2)
W = 450 KJ
From the First Law of Thermodynamics, Q = U + W
So, Heat Transfer = Change in Internal Energy + Work Done
= 13331.618 + 450
Q = 13781.618 kJ/kg
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Answer:
k = 4.21 * 10⁻³(L/(mol.s))
Explanation:
We know that
k = Ae
------------------- euqation (1)
K= rate constant;
A = frequency factor = 4.36 10^11 M⁻¹s⁻¹;
E = activation energy = 93.1kJ/mol;
R= ideal gas constant = 8.314 J/mol.K;
T= temperature = 332 K;
Put values in equation 1.
k = 4.36*10¹¹(M⁻¹s⁻¹)e![^{[(-93.1*10^3)(J/mol)]/[(8.314)(J/mol.K)(332K)}](https://tex.z-dn.net/?f=%5E%7B%5B%28-93.1%2A10%5E3%29%28J%2Fmol%29%5D%2F%5B%288.314%29%28J%2Fmol.K%29%28332K%29%7D)
k = 4.2154 * 10⁻³(M⁻¹s⁻¹)
here M =mol/L
k = 4.21 * 10⁻³((mol/L)⁻¹s⁻¹)
or
k = 4.21 * 10⁻³((L/mol)s⁻¹)
or
k = 4.21 * 10⁻³(L/(mol.s))
