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melisa1 [442]
3 years ago
12

A 25.0 mLsample of an acetic acid solution is titrated with a 0.175 M NaOH solution. The equivalence point is reached when 37.5

mL of the base is added. The concentration of acetic acid in the sample was:_______,
A) 0.263
B) 0.365
C) 0.175
D) 1.83×10−4
E) 0.119
Chemistry
1 answer:
matrenka [14]3 years ago
3 0

Answer:

0.263M of CH₃COOH is the concentration of the solution.

Explanation:

The reaction of acetic acid (CH₃COOH) with NaOH is:

CH₃COOH + NaOH → CH₃COO⁻Na⁺ + H₂O

<em>1 mole of acetic acid reacts per mole of NaOH to produce sodium acetate and water.</em>

<em />

In the equivalence point, moles of acetic acid are equal to moles of NaOH and moles of NaOH are:

0.0375L × (0.175 moles / L) = 6.56x10⁻³ moles of NaOH = moles of CH₃COOH.

As the sample of acetic acid had a volume of 25.0mL = 0.025L:

6.56x10⁻³ moles of CH₃COOH / 0.0250L =

<em>0.263M of CH₃COOH is the concentration of the solution</em>

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Actually, the ionic equation for this is a reversible equation since codeine is a weak base. Any weak base or weak acids do not completely dissociate which makes them a reversible process. The ionic equation for this case is:

<span>C18H21O3N  +  H3O+  </span><=> C18H21O3NH+ +  H2O 

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According to Newton's first law of motion what is required to make an object at rest move
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Hard water often contains dissolved Ca2+ and Mg2+ ions. One way to soften water is to add phosphates. The phosphate ion forms in
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<span>5.5×10−2M in calcium chloride and 8.0×10−2M in magnesium nitrate.
What mass of sodium phosphate must be added to 1.5L of this solution to completely eliminate the hard water ion

1) Content of Ca (2+) ions

Calcium chloride = CaCl2

Ionization equation: CaCl2 ---> Ca (2+) + 2 Cl (-)

=> Molar ratios: 1 mol of CaCl2 : 1 mol Ca(2+) : 2 mol Cl(-)

Calculate the number of moles of CaCl2 in 1.5 liters of 5.5 * 10^-2 M solution

M = n / V => n = M*V = 5.5 * 10^ -2 M * 1.5 l = 0.0825 mol CaCl2

=> 0.0825 mol Ca(2+)

2) Number of phosphate ions needed to react with 0.0825 mol Ca(2+)

formula of phospahte ion: PO4 (3-)

molar ratio: 2PO4(3-) + 3Ca(2+) = Ca3 (PO4)2

Proportion: 2 mol PO4(3-) / 3 mol Ca(2+) = x / 0.0825 mol Ca(2+)

=> x = 0.0825 coml Ca(2+) * 2 mol PO4(3-) / 3 mol Ca(2+) = 0.055 mol PO4(3-)

3) Content of Mg(2+) ions

Ionization equation: Mg (NO3)2 ----> Mg(2+) + 2 NO3 (-)

Molar ratios: 1 mol Mg(NO3)2 : 1 mol Mg(2+) + 2 mol NO3(-)

number of moles of Mg(NO3)2 in 1.5 liter of 8.0 * 10^-2 M solution

n = M * V = 8.0 * 10^ -2 M * 1.5 liter = 0.12 moles Mg(NO3)2

ions of Mg(2+) = 0.12 mol Mg(NO3)2 * 1 mol Mg(2+) / mol Mg(NO3)2 = 0.12 mol Mg(2+)

4) Number of phosphate ions needed to react with 0.12 mol Mg(2+)

2PO4(3-) + 3Mg(2+) = Mg3(PO4)2

=> 2 mol PO4(3-) / 3 mol Mg(2+) = x / 0.12 mol Mg(2+)

=> x = 0.12 * 2/3 mol PO4(3-) = 0.16 mol PO4(3-)

5) Total number of moles of PO4(3-)

0.055 mol + 0.16 mol = 0.215 mol

6) Sodium phosphate

Sodium phosphate = Na3(PO4)

Na3PO4 ---> 3Na(+) + PO4(3-)

=> 1 mol Na3PO4 : 1 mol PO4(3-)

=> 0.215 mol PO4(3-) : 0.215 mol Na3PO4

mass in grams = number of moles * molar mass

molar mass of Na3 PO4 = 3*23 g/mol + 31 g/mol + 4*16 g/mol = 164 g/mol

=> mass in grams = 0.215 mol * 164 g/mol = 35.26 g

Answer: 35.26 g of sodium phosphate
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umka21 [38]

Answer : The value of K_p at this temperature is 66.7

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The balanced equilibrium reaction is,

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The expression of equilibrium constant K_p for the reaction will be:

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Now put all the values in this expression, we get :

K_p=\frac{(10.24)}{(0.348)(0.441)}

K_p=66.7

Therefore, the value of K_p at this temperature is 66.7

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