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2 years ago

If you wanted to prepare a 15.58 L of a 6.25 M solution, what volume of a 14.73 M solution must you start with?

Chemistry

1 answer:

Fed [463]2 years ago

4 0

Answer:

6.61 L

Explanation:

M1 = 6.25

V1 = 15.58

M2 = 14.73

M1V1 = M2V2

(6.25)(15.58) = (14.73)V2

V2 = 6.61 L

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51. The radius of gold is 144 pm and the density is 19.32 g/cm3. Does elemental gold have a face-centered cubic structure or a b

Serjik [45]

Answer:

Elemental gold to have a Face-centered cubic structure.

Explanation:

From the information given:

Radius of gold = 144 pm

Its density = 19.32 g/cm³

Assuming the structure is a face-centered cubic structure, we can determine the density of the crystal by using the following:

$a = \sqrt{8} r$

$a = \sqrt{8} \times 144 pm$

a = 407 pm

In a unit cell, Volume (V) = a³

V = (407 pm)³

V = 6.74 × 10⁷ pm³

V = 6.74 × 10⁻²³ cm³

Recall that:

Net no. of an atom in an FCC unit cell = 4

Thus;

$density = \dfrac{mass}{volume}$

$density = \dfrac{ 4 \ atm ( 196.97 \ g/mol) (\dfrac{1 \ mol }{6.022 \times 10^{23} \ atoms})}{6.74 \times 10^{-23} \ cm^3}$

density d = 19.41 g/cm³

Similarly; For a body-centered cubic structure

$r = \dfrac{\sqrt{3}}{4}a$

where;

r = 144

$144 = \dfrac{\sqrt{3}}{4}a$

$a = \dfrac{144 \times 4}{\sqrt{3}}$

a = 332.56 pm

In a unit cell, Volume V = a³

V = (332.56 pm)³

V = 3.68 × 10⁷ pm³

V 3.68 × 10⁻²³ cm³

Recall that:

Net no. of atoms in BCC cell = 2

∴

$density = \dfrac{mass}{volume}$

$density = \dfrac{ 2 \ atm ( 196.97 \ g/mol) (\dfrac{1 \ mol }{6.022 \times 10^{23} \ atoms})}{3.68 \times 10^{-23} \ cm^3}$

density =17.78 g/cm³

From the two calculate densities, we will realize that the density in the face-centered cubic structure is closer to the given density.

This makes the elemental gold to have a Face-centered cubic structure.

3 0

3 years ago

Dinitrogen pentoxide is used in the preparation of explosives. If 7.93 mol of

Tpy6a [65]

The volume of O₂ produced: 84.6 L

<h3>Further explanation</h3>

Given

7.93 mol of dinitrogen pentoxide

T = 48 + 273 = 321 K

P = 125 kPa = 1,23365 atm

Required

Volume of O₂

Solution

Decomposition reaction of dinitrogen pentoxide

2N₂O₅(g)→4NO₂(g)+O₂ (g)

From the equation, mol ratio N₂O₅ : O₂ = 2 : 1, so mol O₂ :

= 0.5 x mol N₂O₅

= 0.5 x 7.93

= 3.965 moles

The volume of O₂ :

$\tt V=\dfrac{nRT}{P}\\\\V=\dfrac{3.965\times 0.082\times 321}{1.23365}\\\\V=84.6~L$

5 0

3 years ago

Sulfuryl dichloride is formed when sulfur dioxide reacts with chlorine.

zubka84 [21]

<u>Answer:</u> The value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

<u>Explanation:</u>

For the given chemical reaction:

$SO_2(g)+Cl_2(g)\rightarrow SO_2Cl_2(g)$

The equation used to calculate enthalpy change is of a reaction is:

$\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]$

The equation for the enthalpy change of the above reaction is:

$\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]$

We are given:

$\Delta H^o_f_{(SO_2Cl_2(g))}=-364kJ/mol\\\Delta H^o_f_{(SO_2(g))}=-296.8kJ/mol\\\Delta H^o_f_{(Cl_2(g))}=0kJ/mol$

Putting values in above equation, we get:

$\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol$

The equation used to calculate entropy change is of a reaction is:

$\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]$

The equation for the entropy change of the above reaction is:

$\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]$

We are given:

$\Delta S^o_{(SO_2Cl_2(g))}=311.9J/Kmol\\\Delta S^o_{(SO_2(g))}=248.2J/Kmol\\\Delta S^o_{(Cl_2(g))}=223.0J/Kmol$

Putting values in above equation, we get:

$\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol$

To calculate the standard Gibbs's free energy of the reaction, we use the equation:

$\Delta G^o_{rxn}=\Delta H^o_{rxn}-T\Delta S^o_{rxn}$

where,

$\Delta H^o_{rxn}$ = standard enthalpy change of the reaction =-67200 J/mol

$\Delta S^o_{rxn}$ = standard entropy change of the reaction =-159.3 J/Kmol

Temperature of the reaction = 600 K

Putting values in above equation, we get:

$\Delta G^o_{rxn}=-67200-(600\times (-159.3))\\\\\Delta G^o_{rxn}=28380J/mol=28.38kJ/mol$

Hence, the value of $\Delta G^o$ of the reaction is 28.38 kJ/mol

7 0

3 years ago

Question 17

Maurinko [17]

I will say this is True….?

7 0

1 year ago

Read 2 more answers

Which sentences in the passage are true?

user100 [1]

Answer:

First and last sentence .‍♀️

Explanation:

An important thing to keep in mind about the Reading Comprehension section of the GRE as we use PowerPrep online to study is that it is just that—reading comprehension. In other words, as difficult as it may seem, and it can be pretty tricky, the test makers will always give us all the information we need in the passage to answer the question.

7 0

3 years ago