Explanation:
Half life of zero order and second order depends on the initial concentration. But as the given reaction slows down as the reaction proceeds, therefore, it must be second order reaction. This is because rate of reaction does not depend upon the initial concentration of the reactant.
a. As it is a second order reaction, therefore, doubling reactant concentration, will increase the rate of reaction 4 times. Therefore, the statement a is wrong.
b. Expression for second order reaction is as follows:
![\frac{1}{[A]} =\frac{1}{[A]_0} +kt](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%5Cfrac%7B1%7D%7B%5BA%5D_0%7D%20%2Bkt)
the above equation can be written in the form of Y = mx + C
so, the plot between 1/[A] and t is linear. So the statement b is true.
c.
Expression for half life is as follows:
![t_{1/2}=\frac{1}{k[A]_0}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B1%7D%7Bk%5BA%5D_0%7D)
As half-life is inversely proportional to initial concentration, therefore, increase in concentration will decrease the half life. Therefore statement c is wrong.
d.
Plot between A and t is exponential, therefore there is no constant slope. Therefore, the statement d is wrong
Answer:
a. 59 m/atm
Explanation:
- To solve this problem, we must mention Henry's law.
- <em>Henry's law states that at a constant temperature, the amount of a given gas dissolved in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid.</em>
- It can be expressed as: C = KP,
C is the concentration of the solution (C = 1.3 M).
P is the partial pressure of the gas above the solution (P = 0.022 atm).
K is the Henry's law constant (K = ??? M/atm),
∵ C = KP.
∴ K = C/P = (1.3 M)/(0.022 atm) = 59.0 M/atm.
Answer:
384.2 K
Explanation:
First we convert 27 °C to K:
- 27 °C + 273.16 = 300.16 K
With the absolute temperature we can use <em>Charles' law </em>to solve this problem. This law states that at constant pressure:
Where in this case:
We input the data:
300.16 K * 1600 m³ = T₂ * 1250 m³
And solve for T₂:
T₂ = 384.2 K
Answer:
Given, 0.29 g of hydrocarbon produces 448ml of CO2 at STP. then, C2H5 is the emperical formula of hydrocarbon . n = 2 , hence, molecular formula will be C4H10
Answer:
B
Explanation:
Light travels faster than sound.
