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Aleks04 [339]
4 years ago
10

A chemist wants to extract copper metal from copper chloride solution. The chemist places 0.50 grams of aluminum foil in a solut

ion containing 0.75 grams of copper (II) chloride. A single replacement reaction takes place. Which statement explains the maximum amount of copper that the chemist can extract using this reaction? Approximately 0.36 grams, because copper (II) chloride acts as a limiting reactant Approximately 1.8 grams, because copper (II) chloride acts as a limiting reactant Approximately 0.36 grams, because aluminum acts as a limiting reactant Approximately 1.8 grams, because aluminum acts as a limiting reactant
Chemistry
1 answer:
Irina-Kira [14]4 years ago
5 0

Answer:

Approximately 0.36 grams, because copper (II) chloride acts as a limiting reactant.

Explanation:

  • It is a stichiometry problem.
  • We should write the balance equation of the mentioned chemical reaction:

<em>2Al + 3CuCl₂ → 3Cu + 2AlCl₃.</em>

  • It is clear that 2.0 moles of Al foil reacts with 3.0 moles of CuCl₂ to produce 3.0 moles of Cu metal and 2.0 moles of AlCl₃.
  • Also, we need to calculate the number of moles of the reported masses of Al foil (0.50 g) and CuCl₂ (0.75 g) using the relation:

<em>n = mass / molar mass</em>

  • The no. of moles of Al foil = mass / atomic mass = (0.50 g) / (26.98 g/mol) = 0.0185 mol.
  • The no. of moles of CuCl₂ = mass / molar mass = (0.75 g) / (134.45 g/mol) = 5.578 x 10⁻³  mol.
  • <em>From the stichiometry Al foil reacts with CuCl₂ with a ratio of 2:3.</em>

∴ 3.85 x 10⁻³  mol of Al foil reacts completely with 5.578 x 10⁻³  mol of CuCl₂ with <em>(2:3)</em> ratio and CuCl₂ is the limiting reactant while Al foil is in excess.

  • From the stichiometry 3.0 moles of  CuCl₂ will produce the same no. of moles of copper metal (3.0 moles).
  • So, this reaction will produce 5.578 x 10⁻³ mol of copper metal.
  • Finally, we can calculate the mass of copper produced using:

mass of Cu = no. of moles x Atomic mass of Cu = (5.578 x 10⁻³  mol)(63.546 g/mol) = 0.354459 g ≅ 0.36 g.

  • <u><em>So, the answer is:</em></u>

<em>Approximately 0.36 grams, because copper (II) chloride acts as a limiting reactant.</em>

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1 mol super cooled liquid water transformed to solid ice at -10 oC under 1 atm pressure.
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Answer:

Explanation:

Given that:

number of moles of super cooled liquid water = 1

Melting enthalpy of ice = 6020 J/mol

Freezing point =0 °C = (0 + 273 K)= 273 K

The decrease in entropy of the system during freezing for 1 mol (i.e during transformation from liquid water to solid ice )  = - 6020 J/mol × 1 mol /273 K = -22.051 J/K

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Entropy change of universe = entropy change of the system+ entropy change of the surrounding

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Entropy change in the surrounding > 23.53 J/K

b) Make some comments on entropy changes from the obtained data.

From the data obtained; we will realize that the entropy of the system decreases as cooling takes place when water is be convert to ice , randomness of these molecules reduces and as cooling proceeds , hence, entropy reduces more as well and the liberated heat will go into the surrounding due to this entropy of the surrounding increasing.

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So in this case as the concentration of NaOH is not known,NaOH is the analyte.

Titrant is the solution whose concentration  is known to us and is added to an analyte until the equivalence point is reached. In this case since we know the concentration of HCl, HCl is the titrant.


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