The industrial synthesis of ammonia is spontaneous.
to to prove this one calculate the gibbs free energy(delta G)
= delta G = Delta H -T delta s
delta H = -92.2 kj in joules -92.2 x1000 =-92200j
delta s = -199j/k
T= 25+273= 298k
delta G is therefore= -92200-298(-199)=-32898j
since delta G is negative the reaction is therefore spontaneous
Answer:
The number of electrons in the outermost shell of an atom determines its reactivity. Noble gases have low reactivity because they have full electron shells. Halogens are highly reactive because they readily gain an electron to fill their outermost shell.
Explanation:
Answer: The pH of phenol solution is 4.7
Explanation:
pH or pOH is the measure of acidity or alkalinity of a solution.
pH is calculated by taking negative logarithm of hydronium ion concentration.
![pH=-\log [H_3O^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH_3O%5E%2B%5D)
Given : ![[H_3O^+]=1.8\times 10^{-5}M](https://tex.z-dn.net/?f=%5BH_3O%5E%2B%5D%3D1.8%5Ctimes%2010%5E%7B-5%7DM)
Putting in the values we get
![pH=-\log[1.8\times 10^{-5}M]](https://tex.z-dn.net/?f=pH%3D-%5Clog%5B1.8%5Ctimes%2010%5E%7B-5%7DM%5D)

Thus pH of phenol solution is 4.7
Explanation:
The sulfonation of the naphthalene yield 2 products under different conditions:
<u>When the reaction is carried at 80 °C, 1-naphthalenesulfonic acid is the major product because it is kinetically favoured product as arenium ion formed in the transition state corresponding to 1-naphthalenesulfonic acid is more stable due to better resonance stabilization.
</u>
<u>When the reaction is carried at 160 °C, 2-naphthalenesulfonic acid is the major product as it is more stable than 1-naphthalenesulfonic acid because of steric interaction of the sulfonic acid group in 1-position and the hydrogen in 8-position.</u>
The products are shown in image below.
V₁ = <span>178 mL - initial volume
</span>T₁ = 0 ⁰C = 273K - initial temperature
V₂ = <span>211 mL - final volume
</span>T₂ =? - final temperature
According to Charles's law when pressure is constant the Kelvin temperature and the volume will be directly related:
V₁/T₁=V₂/T₂
178/273=211/T₂
0.65=211/T₂
T₂=324K= 51⁰C