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-Dominant- [34]
3 years ago
9

The molar mass of a substance is 92.010g. The substance is 30.4% nitrogen and 69.9% oxygen. What is the empirical formula and th

e molecular formula of the substance
Chemistry
1 answer:
Veronika [31]3 years ago
6 0

Answer:

Empirical formula = NO₂

Molecular formula = N₂O₄

Explanation:

Percentage mass of Nitrogen = 30.4 %

Percentage mass of Oxygen = 60.9 %

Mole ratio of the elements:

Nitrogen = 30.4/14 = 2.17

Oxygen = 69.9/16 = 4.37

Dividing by the smallest ratio to obtain a simple ratio

Nitrogen: 2.17/2.17 = 1

Oxygen; 4.37/2.17 = 2

Therefore, the simplest mole ratio is 1:2

Empirical formula = NO₂

Molecular formula = n(empirical formula), therefore, molecular mass = n *(empirical mass)

92.010 = n(14 + 32)

92.010 = 46n

n = 92.010/46

n = 2

Therefore, molecular formula = 2(NO₂)

Molecular formula = N₂O₄

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For the given chemical equations:

NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}

Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9

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The expression for equilibrium constant of above equation is:

K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}

As, NiC_2O_4 is a solid, so its activity is taken as 1 and so for C_2O_4^{2-}

We are given:

[[Ni(NH_3)_6]^{2+}]=0.016M

Putting values in above equations, we get:

0.48=\frac{0.016}{[NH_3]^6}}

[NH_3]=0.285M

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