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Mariulka [41]
3 years ago
8

The following mechanism has been proposed for the conversion of tert-butyl bromide to tert-butyl alcohol in aqueous solution: st

ep 1: (CH3)3CBr (CH3)3C Br- step 2: (CH3)3C OH- (CH3)3COH (a) Identify the molecularity of each step in the mechanism. step 1 unimolecular step 2 bimolecular (b) Write the equation for the net reaction. Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (c) Identify any intemediates in this mechanism. Intermediate: Enter formula. If none, leave box blank:
Chemistry
1 answer:
Gelneren [198K]3 years ago
8 0

Answer:

See explanation

Explanation:

The first step in this reaction is a unimolecular reaction. It involves the formation of the carbocation. This is so because tertiary alkyl halides only undergo substitution by SN1 mechanism due to sterric crowding.

The second step in the reaction is bi molecular. In this step, the carbocation now combines with the OH^- to yield the alcohol.

Net equation of the reaction is;

(CH3)3CBr + OH^- -------> (CH3)3COH + Br^-

The intermediate here is the carbocation,  (CH3)3C^+

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The molar heat of fusion of gold is 12.550 kJ mol–1. At its melting point, how much mass of melted gold must solidify to release
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The mass of melted gold to release the energy would be  3, 688. 8 Kg

<h3>How to determine the mass</h3>

The formula for quantity of energy is given thus;

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Where n represents number of moles

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To find the number of moles, we have

235.0 = n × 12.550

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Note that molar mass of Gold is 197g/ mol

Let's note that;

Number of moles = mass/ molar mass

Mass = number of moles × molar mass

Mass = 18. 725 × 197

Mass = 3, 688. 8 Kg

Thus, the mass of melted gold to release the energy would be  3, 688. 8 Kg

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The solubility of kcl in ethanol is 0.25 g / 100 ml at 25 oc. how does this compare to the solubility of kcl in water?
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Britney added 0.05 moles of copper(II) nitrate solution to 0.1 moles of sodium hydroxide solution and
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The percent yield of copper hydroxide is 84%

<h3>Stoichiometry</h3>

From the question, we are to determine the percent yield of copper hydroxide

First, we will determine the theoretical mass

From the given balanced chemical equation, we have

Cu(NO₃)₂ + 2NaOH -- Cu(OH)₂ + 2NaNO₃

This means,

1 mole of copper(II) nitrate reacts with 2 moles of sodium hydroxide to produce 1 mole of copper hydroxide

Therefore,
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The theoretical number of moles of copper hydroxide that is produced is 0.05 mole

Now, for the theoretical mass

Using the formula,

Mass = Number of moles × Molar mass

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Then,

Theoretical mass = 0.05 × 97.56

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Now, for the percent yield of copper hydroxide

Percent yield is given by the formula,

Percent\ yield = \frac{Actual\ yield}{Theoretical\ yield} \times 100\%

Then,

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Hence, the percent yield of copper hydroxide is 84%.

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