With a graduated cylinder, you are most likely measuring mL (milliliters) or volume of a liquid, or the mass of a liquid.
I think it’s a maybe hope this helps
Answer:
Units of a = 
Units of b = 
Explanation:
The Van der Waal's equation is:-

Where,
P is the pressure
V is the volume
n is the number of moles
T is the temperature
R is Gas constant having value
a and b are van der Waal's constant
If pressure is taken in atm and volume in L. So,
represents the pressure correction term. Then,
Units of a = 
represents the volume correction term. Then,
Units of b = 
The trophosphere contains the most water vapor!