The oxidation number of O is -2 and there's 4 of them so the total is -8. Since it's a molecule the sum of the oxidation numbers of the atoms must equal 0. If 4 oxygen atoms have an oxidation number of -8 then the two S atoms must is +8 to equal 0 so the oxidation number of the S is 8/2 = +4
Answer:
d. 60.8 L
Explanation:
Step 1: Given data
- Heat absorbed (Q): 53.1 J
- External pressure (P): 0.677 atm
- Final volume (V2): 63.2 L
- Change in the internal energy (ΔU): -108.3 J
Step 2: Calculate the work (W) done by the system
We will use the following expression.
ΔU = Q + W
W = ΔU - Q
W = -108.3 J - 53.1 J = -161.4 J
Step 3: Convert W to atm.L
We will use the conversion factor 1 atm.L = 101.325 J.
-161.4 J × 1 atm.L/101.325 J = -1.593 atm.L
Step 4: Calculate the initial volume
First, we will use the following expression.
W = - P × ΔV
ΔV = - W / P
ΔV = - 1.593 atm.L / 0.677 atm = 2.35 L
The initial volume is:
V2 = V1 + ΔV
V1 = V2 - ΔV
V1 = 63.2 L - 2.35 L = 60.8 L
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