35 b.
37 h
39 i
41 d
hope that helps
Balancing of chemical equation is essential because of the law of conservation of mass, which states that the mass of a system can not be created or removed.
The second equation is balanced
This is because the number of elements of each atom in the product side equal the number of elements of each atom on the reactant side.
The first equation is not balanced

This is because there is 1 molecule of
on reactant side as compared to 3 molecules of 
To balance the equation we add a coefficient of 3 on sulphuric acid (
) and a coefficient of 3 on hydrogen (
)

The amount or disorder in a chemical system or system is measured by it's Entropy. Entropy is the simply the measure of the amount of disorder or lack of structure present within a system.
There are 70.90g of Cl2 in 1 mol (because 35.45g Cl in one mol). So 77.1g/70.9g≈1.0874 mol.