Answer:
See explanation below
Explanation:
To get a better understanding watch the picture attached.
In the case of the reaction with Bromine, the -N(CH₃)₂ is a strong ring activator, therefore, it promotes a electrophilic aromatic sustitution, so, in the mechanism of reaction, the lone pair of the Nitrogen, will move to the ring by resonance and activate the ortho and para positions. That's why the bromine wil go to the ortho and para positions, mostly the para position, because the -N(CH₃)₂ cause a steric hindrance in the ortho position.
In the case of the reaction with HNO₃/H₂SO₄, the acid transform the -N(CH₃)₂ in a protonated form, the anilinium ion, which is a deactivating of the ring, and also a strong electron withdrawing, so, the electrophile will go to the meta position instead.
Hope this helps.
<span>a.they both weight exactly the same.</span>
Answer:
Reaction 1: Kc increases
Reaction 2: Kc decreases
Reaction 3: The is no change
Explanation:
Let us consider the following reactions:
Reaction 1: A ⇌ 2B ΔH° = 20.0 kJ/mol
Reaction 2: A + B ⇌ C ΔH° = −5.4 kJ/mol
Reaction 3: 2A⇌ B ΔH° = 0.0 kJ/mol
To predict what will happen when the temperature is raised we need to take into account Le Chatelier Principle: when a system at equilibrium suffers a perturbation, it will shift its equilibrium to counteract such perturbation. This means that <em>if the temperature is raised (perturbation), the system will react to lower the temperature.</em>
Reaction 1 is endothermic (ΔH° > 0). If the temperature is raised the system will favor the forward reaction to absorb heat and lower the temperature, thus increasing the value of Kc.
Reaction 2 is exothermic (ΔH° < 0). If the temperature is raised the system will favor the reverse reaction to absorb heat and lower the temperature, thus decreasing the value of Kc.
Reaction 3 is not endothermic nor exothermic (ΔH° = 0) so an increase in the temperature will have no effect on the equilibrium.
The flow of electricity is an electric current. The path that an electric currents floes is a circuit.