Answer: The rate of appearance of 
is 
Explanation:
Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.
Rate in terms of disappearance of HBr = ![-\frac{1d[HBr]}{2dt}Rate in terms of appearance of [tex]H_2](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BHBr%5D%7D%7B2dt%7D%3C%2Fp%3E%3Cp%3ERate%20in%20terms%20of%20appearance%20of%20%5Btex%5DH_2)
= ![\frac{1d[H_2]}{dt}](https://tex.z-dn.net/?f=%5Cfrac%7B1d%5BH_2%5D%7D%7Bdt%7D)
Rate in terms of appearance of = ![\frac{1d[Br_2]}{dt}](https://tex.z-dn.net/?f=%5Cfrac%7B1d%5BBr_2%5D%7D%7Bdt%7D)
![-\frac{1d[HBr]}{2dt}=\frac{d[H_2]}{dt}=\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BHBr%5D%7D%7B2dt%7D%3D%5Cfrac%7Bd%5BH_2%5D%7D%7Bdt%7D%3D%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Given :
![-\frac{1d[HBr]}{dt}=0.140Ms^{-1}](https://tex.z-dn.net/?f=-%5Cfrac%7B1d%5BHBr%5D%7D%7Bdt%7D%3D0.140Ms%5E%7B-1%7D)
The rate of appearance of ;
![\frac{1d[Br_2]}{dt}=-\frac{1d[HBr]}{2dt}=\frac{1}{2}\times 0.140=0.0700Ms^{-1}](https://tex.z-dn.net/?f=%5Cfrac%7B1d%5BBr_2%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1d%5BHBr%5D%7D%7B2dt%7D%3D%5Cfrac%7B1%7D%7B2%7D%5Ctimes%200.140%3D0.0700Ms%5E%7B-1%7D)
Thus rate of appearance of is
The total pressure of the mixture of gases is
equal to the sum of the pressure of each gas as if it is alone in the
container. The partial pressure of a component of the mixture is said to be
equal to the product of the total pressure and the mole fraction of the
component in the mixture.<span>
Partial pressure of hydrogen gas = 1.24 atm x
.25 = 0.31 atm
<span>Partial pressure of the remaining = 1.24 atm x
(1-.25) = 0.93 atm </span></span>
Answer:
1. There most not be rotation within the molecule.
2. Two non identical group must be present in the double bonded carbon atom.
Explanation:
This is because cis/ trans isomerism are that exhibit different structural configurations where the atoms are spartially arranged. They are also refered to as geometric isomers. They cannot be interconverted at room temperature because it requires the bonds to be broken and restructured.
Cis shows that the functional groups on present in the same side which trans isomerism show that the functional groups are on opposite sides.
