Answer: -
15.55 M
35.325 molal
Explanation: -
Let the volume of the solution be 1000 mL.
Density of nitric acid = 1.42 g/ mL
Total Mass of nitric acid Solution = Volume of nitric acid x Density of nitric acid
= 1000 mL x 1.42 g/ mL
= 1420 g.
Percentage of HNO₃ = 69%
Amount of HNO₃ = 
= 979.8 g
Molar mass of HNO₃ = 1 x 1 + 14 x 1 + 16 x 3 = 63 g /mol
Number of moles of HNO₃ = 
= 15.55 mol
Molarity is defined as number of moles per 1000 mL
We had taken 1000 mL as volume and found it to contain 15.55 moles.
Molarity of HNO₃ = 15.55 M
Mass of water = Total mass of nitric acid solution - mass of nitric acid
= 1420 - 979.8
= 440.2 g
So we see that 440.2 g of water contains 15.55 moles of HNO₃
Molality is defined as number of moles of HNO₃ present per 1000 g of water.
Molality of HNO₃ = 
= 35.325 molal
The molarity of a hydrochloric acid solution : 0.32 M
<h3>Further explanation </h3>
Titration is a procedure for determining the concentration of a solution by reacting with another solution which is known to be concentrated (usually a standard solution).
Titrations can be distinguished including acid-base titration, depositional titration, and redox titration. An acid-base titration is the principle of neutralization of acids and bases is used.
Acid-base titration formula
Ma. Va. na = Mb. Vb. nb
Ma, Mb = acid base concentration
Va, Vb = acid base volume
na, nb = acid base valence
1 ⇒HCl (valence=1, HCl ⇒H⁺+Cl⁻, one H⁺)
2⇒Ca(OH)₂(valence=2, Ca(OH)₂⇒Ca²⁺+2OH⁻, two OH⁻)
M₂=0.1 M
V₂=48 ml=0.048 L
V₁=30 ml=0.03 L

Ok, after doing an immense amount of research I came up with the most logical answer.
A. Is indicated by a negative enthrall sign.
Reasoning: an endothermic reaction is ice melting and the energy being more than its surroundings. Not specified to ice but as an example, ice is endothermic. That puts d and b out of the running leaving you left with a and c.
When I searched up enthalpy, it said “When a substance changes at constant pressure, enthalpy tells how much heat and work was added or removed from the substance.” Which is similar to c, right? Yeah, meaning both a and c are similar in that aspect.
The reason I decided to go with a is because heat is NOT released into the surrounding, exothermic reactions release energy and heat into the surrounding.