What has more mass 100 apples or 100 grapes? Why?
2 answers:
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Explanation:
Dehydrohalogenation reactions occurs as elimination reactions through the following mechanism:
Step 1: A strong base(usually KOH) removes a slightly acidic hydrogen proton from the alkyl halide.
Step 2: The electrons from the broken hydrogen‐carbon bond are attracted toward the slightly positive carbon (carbocation) atom attached to the chlorine atom. As these electrons approach the second carbon, the halogen atom breaks free.
However, elimination will be slower in the exit of Hydrogen atom at the C2 and C3 because of the steric hindrance by the methyl group.
Elimination of the hydrogen from the methyl group is easier.
Thus, the major product will A
Answer:
Heat transfer in step 2 = 47.75 J
Explanation:
Internal energy = heat + work done
U = Q + W
In a cyclic process the total internal energy change of the system = 0.
In the process there are two steps. The total heat exchange in the process is the sum of heat exchanges in the two processes.
We have to find the heat exchange in step 2.
In step 1,
W = 1.25 J Q = -37 J
= -37 + 1.25 = -35.75 J
In step 2, the internal energy change will be negative of that in step 1.
U = 35.75 J
W = -12 J
U = Q + W
35.75 = Q -12
Q = 47.75 J
Heat transfer in step 2 = 47.75 J