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Varvara68 [4.7K]
3 years ago
10

You must make 1 L of 0.2 M acetic acid (CH3COOH). All you have available is concentrated glacial acetic acid (assay value, 98%;

specific gravity, 1.05 g/mL). It will take _________ milliliters of acetic acid to make this solution. Assume a gram molecular weight of 60.05 grams.
Chemistry
1 answer:
Sergeu [11.5K]3 years ago
7 0

Answer:

The correct answer is "11.44 ml".

Explanation:

Molarity,

= 0.2 M

Density,

= 1.05 g/ml

Volume,

= 1 L

As we know,

⇒  Molarity=\frac{No. \ of \ moles }{Volume \ of \ solution}

or,

⇒  No. \ of \ moles=Molarity\times Volume

On putting the values, we get

⇒                         =0.2\times 1

⇒                         =0.2 \ moles

Now,

⇒  No. \ of \ moles=\frac{Mass \ taken}{Molecular \ mass}

or,

⇒  Mass \ taken=No. \ of \ moles\times Molecular \ mass

⇒                      =0.2\times 60.05

⇒                      =12.01 \ gram

hence,

⇒  Density= \frac{Mass }{Volume}

or,

⇒  Volume=\frac{Mass}{Density}

⇒                =\frac{12.01}{1.05}

⇒                =11.44 \ ml

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<h3>Further explanation</h3>

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<u>Given:</u>

A mysterious white powder could be,

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When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

  • The solute = the powder
  • The solvent = ethanol
  • The freezing point of the solvent = −114.6°C
  • The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

  • Mass of solute = 82 mg = 0.082 g
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We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

Now we combine it with the formula of freezing point depression.

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It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }

\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }

\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }

We get \boxed{ \ Mr = 153.65 \ }

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>
  1. The molality and mole fraction of water brainly.com/question/10861444
  2. About the mass and density of ethylene glycol as an  antifreeze brainly.com/question/4053884
  3. About the solution as a homogeneous mixture  brainly.com/question/637791

Keywords: a mysterious white powder, sugar, cocaine, codeine, norfenefrine, fructose, the solute, the solvent, dissolved, ethanol, normal freezing point, the freezing point depression, the identity

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