Answer:
0.364
Explanation:
Let's do an equilibrium chart for the reaction of combustion of ammonia:
2NH₃(g) + (3/2)O₂(g) ⇄ N₂(g) + 3H₂O(g)
4.8atm 1.9atm 0 0 Initial
-2x -(3/2)x +x +3x Reacts (stoichiometry is 2:3/2:1:3)
4.8-2x 1.9-(3/2)x x 3x Equilibrium
At equilibrium the velocity of formation of the products is equal to the velocity of the formation of the reactants, thus the partial pressures remain constant.
If pN₂ = 0.63 atm, x = 0.63 atm, thus, at equilibrium
pNH₃ = 4.8 - 2*0.63 = 3.54 atm
pO₂ = 1.9 -(3/2)*0.63 = 0.955 atm
pH₂O = 3*0.63 = 1.89 atm
The pressure equilibrium constant (Kp) is calculated with the partial pressure of the gases substances:
Kp = [(pN₂)*(pH₂O)³]/[(pNH₃)²*
]
Kp = [0.63*(1.89)³]/[(3.54)²*
]
Kp = 4.2533/11.6953
Kp = 0.364
Answer : The work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Explanation :
(a) At constant volume condition the entropy change of the gas is:

We know that,
The relation between the
for an ideal gas are :

As we are given :



Now we have to calculate the entropy change of the gas.


(b) As we know that, the work done for isochoric (constant volume) is equal to zero. 
(C) Heat during the process will be,

Therefore, the work, heat during the process and the change of entropy of the gas are, 0 J, 3333.003 J and -10 J respectively.
Answer:
The solubility product of lead(II) chloride is
.
Explanation:
Concentration of lead (II) ions = ![[Pb^{2+}]=0.0159 M](https://tex.z-dn.net/?f=%5BPb%5E%7B2%2B%7D%5D%3D0.0159%20M)
Concentration of chloride ion = ![[Cl^-]=0.0318 M](https://tex.z-dn.net/?f=%5BCl%5E-%5D%3D0.0318%20M)

The expression of a solubility product will be given as:
![K_{sp}=[Pb^{2+}][Cl^-]^2](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BPb%5E%7B2%2B%7D%5D%5BCl%5E-%5D%5E2)

The solubility product of lead(II) chloride is
.
Answer:
3.27 x 10⁻¹⁶ grams
Explanation:
moles Au = 1.00 x 10⁻⁶ Atoms / 6.02 x 10²³Atoms / mole = 1.66 x 10⁻¹⁸ mole Au
grams Au = 1.66 x 10⁻¹⁸ mole Au x 196.97 grams Au/mole Au
= 3.27 x 10⁻¹⁶ grams Au