Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104![[P(NO_{2} )]^{2}](https://tex.z-dn.net/?f=%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D)
+ 
- 200 = 0
Resolving the second degree equation:
= 
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer:
The three-step synthesis of trans-2-pentene from acetylene is as follows.
<u>Step -1:</u> Formation of higher order terminal alkyne on reaction with sodium acetylides with haloalkanes.
<u>Step -2:</u> Formation terminal alkyne to nonterminal alkynes.
<u>Step -3:</u> Formation of trans-pent - 2-pent-ene by reduction.
Explanation:
Synthesis of trans-pent-2-yne from ethyne takes place is mainly a three step synthesis which involves formation of higher order terminal alkyne on reaction with sodium acetylides with haloalkane. Second step involves the further alkylation of terminal alkynes to higher order nonterminal alkynes and the third step involves the formation of trans-2-ene by dissolving reduction method.
The chemical reaction of each step of chemical reactions is as follows.
Kilometers, Meters and centimeters if metric
Feet, inches, yards and miles if customary ( u.s.)
The mass of nickel, Ni deposited when 0.2 faraday of electrical charge is passed through a solution of NiSO₄ is 5.9 g
