Answer:
Steam always has more thermal energy than ice.
Explanation:
a) First, to get ΔG°rxn we have to use this formula when:
ΔG° = - RT ㏑ K
when ΔG° is Gibbs free energy
and R is the constant = 8.314 J/mol K
and T is the temperature in Kelvin = 25 °C+ 273 = 298 K
and when K = 4.4 x 10^-2
so, by substitution:
ΔG°= - 8.314 * 298 *㏑(4.4 x 10^-2)
= -7739 J = -7.7 KJ
b) then, to get E° cell for a redox reaction we have to use this formula:
ΔE° Cell = (RT / nF) ㏑K
when R is a constant = 8.314 J/molK
and T is the temperature in Kelvin = 25°C + 273 = 298 K
and n = no.of moles of e- from the balanced redox reaction= 3
and F is Faraday constant = 96485 C/mol
and K = 4.4 x 10^-2
so, by substitution:
∴ ΔE° cell = (8.314 * 298 / 3* 96485) *㏑(4.4 x 10^-2)
= - 2.7 x 10^-2 V
Answer:
The Law of Conservation of Energy states that energy cannot be created or destroyed. In other words, the total energy of a system remains constant. This is an important concept to remember when dealing with energy problems. The two basic forms of energy that we will focus on are kinetic energy and potential energy.
Explanation:
In physics and chemistry, the law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be conserved over time. This law means that energy can neither be created nor destroyed; rather, it can only be transformed or transferred from one form to another.
Im bad at these questions hope it helps and have a good day.
Calculate the ratio by using Henderson-Hasselbalch equation:
pH = pKa + log [neutral form] / Protonated form
3.05 = 2.21 + log [neutral form] / [Protonated form]
3.05 - 2.21 = log [neutral form] / [Protonated form]
0.84 = log [neutral form] / [Protonated form]
[neutral form] / [protonated form] = anti log 0.84 = 6.91
Answer:
56.9 mmoles of acetate are required in this buffer
Explanation:
To solve this, we can think in the Henderson Hasselbach equation:
pH = pKa + log ([CH₃COO⁻] / [CH₃COOH])
To make the buffer we know:
CH₃COOH + H₂O ⇄ CH₃COO⁻ + H₃O⁺ Ka
We know that Ka from acetic acid is: 1.8×10⁻⁵
pKa = - log Ka
pKa = 4.74
We replace data:
5.5 = 4.74 + log ([acetate] / 10 mmol)
5.5 - 4.74 = log ([acetate] / 10 mmol)
0.755 = log ([acetate] / 10 mmol)
10⁰'⁷⁵⁵ = ([acetate] / 10 mmol)
5.69 = ([acetate] / 10 mmol)
5.69 . 10 = [acetate] → 56.9 mmoles