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yanalaym [24]
2 years ago
9

If the molar heat of combustion of liquid benzene at constant volume and 300k is -3272KJ. Calculate the heat of combustion at co

nstant pressure at thesame temperature
Chemistry
1 answer:
vladimir2022 [97]2 years ago
4 0

Answer:

The heat at constant pressure is -3,275.7413 kJ

Explanation:

The combustion equation is 2C₆H₆ (l) + 15O₂ (g)  → 12CO₂ (g) + 6H₂O (l)

\Delta n_g = (12 - 15)/2 = -3/2

We have;

\Delta H = \Delta U + \Delta n_g\cdot R\cdot T

Where R and T are constant, and ΔU is given we can write the relationship as follows;

H = U + \Delta n_g\cdot R\cdot T

Where;

H = The heat at constant pressure

U = The heat at constant volume = -3,272 kJ

\Delta n_g = The change in the number of gas molecules per mole

R = The universal gas constant = 8.314 J/(mol·K)

T = The temperature = 300 K

Therefore, we get;

H = -3,272 kJ + (-3/2) mol ×8.314 J/(mol·K) ×300 K) × 1 kJ/(1000 J) = -3,275.7413 kJ

The heat at constant pressure, H = -3,275.7413 kJ.

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An object in motion <u>stays</u> <u>at</u> motion An object <u>at</u> <u>rest</u> stays at rest unless acted by an <u>external</u> force.

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2 years ago
Which element has a larger atomic radius than sulfur? chlorine cadmium fluorine oxygen
zhuklara [117]

Answer:

  • <u>Cadmium has larger atomic radius than sulfur.</u>

Explanation:

Down a period, atomic radii decrease from left to right due to the increase in the number of protons and electrons across a period: when a proton is added the pull of the electrons towards the nucleus is larger, so the size of the atom decreases.

Hence, you can compare the elements that belong to a same period and predict that the atom with lower atomic number (number of protons) will haver larger atomic radius. With that:

  • Oxygen and fluorine are in the period 3, being oxygen to the left of fluorine, so oxygen is larger than fluorine.

  • Sulfur and chlorine are in the period 4, being sulfur to the left of chlorine, so sulfur is larger than chlorine.

Now see whan happens down a group. Atomic radius increases from top to bottom within a group due to electron shielding. That permits you to compare the size of the elements in a group:

  • Fluorine and chlorine are in the same group (17), with chlorine directly below fluorine, so the atomic radius of chlorine is larger than the atomic radius of fluorine.

  • Sulfur and oxygen are in the same group (16), with sulfur directlly below oxygen, so sulfur the atomic radius of sulfur is larger than the atocmi radius of oxygen.

So far, you can rank the atomic radius of sulfur, chlorine, fluorine, and oxygen, in increasing order as:

  • O < F < Cl < S, concluding that O, F, and Cl have smaller atomic radius than S.

Cadmiun, Cd, is to the left and below sulfur, so both electron shielding (down a group) and increase of the number of protons (down a period) lead to predict the cadmium has a larger atomic radius than sulfur.

8 0
3 years ago
When .080 moles of propane burn at STP, what volume of carbon dioxide is produced?
ahrayia [7]

Taking into account the reaction stoichiometry and the definition of STP, 5.4 L of carbon dioxide is produced.

<h3>Reaction stoichiometry</h3>

In first place, the balanced reaction is:

C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • C₃H₈: 1 mole
  • O₂: 5 moles
  • CO₂: 3 moles
  • H₂O: 4 moles

<h3>Moles of CO₂ formed</h3>

The following rule of three can be applied: if by reaction stoichiometry 1 mole of C₃H₈ form 3 moles of CO₂, 0.080 moles of C₃H₈ form how many moles of CO₂?

amount of moles of CO_{2} =\frac{0.080 moles of C_{3} H_{8}x3 moles of CO_{2} }{1 mole of C_{3} H_{8} }

<u><em>amount of moles of CO₂= 0.24 moles</em></u>

<h3>Definition of STP condition</h3>

The STP conditions refer to the standard temperature and pressure. Pressure values at 1 atmosphere and temperature at 0 ° C are used and are reference values for gases. And in these conditions 1 mole of any gas occupies an approximate volume of 22.4 liters.

<h3>Volume of CO₂ produced</h3>

You can apply the following rule of three: If by definition of STP 1 mole of CO₂ occupies 22.4 L, 0.24 moles of CO₂ how much volume does it occupy?

volume of CO_{2} =\frac{0.24 molesx22.4 L}{1 mole}

<u><em>volume of CO₂= 5.376 L ≅ 5.4 L</em></u>

Finally, 5.4 L of carbon dioxide is produced.

Learn more about

the reaction stoichiometry:

<u>brainly.com/question/24741074</u>

<u>brainly.com/question/24653699</u>

STP conditions:

<u>brainly.com/question/26364483</u>

<u>brainly.com/question/8846039</u>

<u>brainly.com/question/1186356</u>

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1 year ago
A topographical map would be useful for which activity? A. planning a hiking trip B. studying plant growth over time C. studying
amm1812
The answer is A. planning a hiking trip

A topographical map would not help studying plant growth over time unless you are looking for a better altitude to plant said plants.

A topographical map would not help studying rainfall for one year unless your location was <em>really</em> so high or low that it affected your weather

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A topographical map <em>would</em> be useful for planning a hiking trip because there are many factors and details that a hike should have. Which includes height, distance, paths, and elevation.
5 0
3 years ago
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