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umka2103 [35]
3 years ago
10

What are the limitations of the van der Waals equation.​

Chemistry
1 answer:
jeka57 [31]3 years ago
8 0
Limitations of Van der waal's equation. (i) The value of 'b' is not constant but varies with pressure and temperature. (ii) The value of is not equal to 3b, but actually it is equal to, in some case; and in other cases 2b. (iii) The value of is not equal to but it is usually more than 3 for most of the gases.
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When a neutral atom gains or loses electrons, it becomes charged and is called a​
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balu736 [363]

Explanation:

Given -

  • An organic compound gives H₂ gas with Na
  • On treatment with alkaline iodine it gives yellow ppt.
  • On oxidation with CrO₃/H⁺ forms an aldehyde (C₂H₄O)

To Find -

  • Name the compound and write the reaction involved

Now,

Let A be the organic compound.

Then,

  1. A + Na → + H₂↑
  2. A + I₂ → CHI₃ (yellow ppt.)
  3. A + CrO₃ + H⁺ → C₂H₄O

Now,

Here we see that compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives aldehyde.

  • Functional group of aldehyde = —CHO

And It forms only 2 Carbon aldehyde it means, It is Ethanal (CH₃CHO).

Compound A reacts with chromic oxide (CrO₃) in the presence of acidic medium gives ethanal.

It means,

We know that 1° alcohol on oxidation gives aldehyde.

Here it gives 2 Carbon aldehyde.

It means,

Here 2 Carbon and 1° alcohol is used.

Now,

Its cleared that Compound A is Ethanol.

Reaction Involved -

  1. CH₃CH₂OH + Na → CH₃CH₂O⁻Na⁺ + H₂↑
  2. CH₃CH₂OH + I₂ + OH⁻ → CHI₃↓ + HCOO⁻ + HI + H₂O
  3. CH₃CH₂OH + CrO₃ + H⁺ → CH₃CHO

6 0
3 years ago
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