I believe the first space is 1. alloys, and the second space is also 1. main. I don't know for sure but I hope this helps.
As per the rule, oxidation number of alkaline earth metals in their compounds is +2. Oxidation number of oxygen in it's compounds is -2(except peroxides) and the sum of oxidation numbers of all the elements of a neutral compound is zero.
The asthenosphere is directly below the lithosphere so the answer to your question is the asthenosphere, because the outer core is towards the center of Earth.