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Answer:- 3. and
Explanations:- An empirical formula is the simplest whole number ratio of atoms of each element present in the molecule/compound.
For example, the molecular formula of benzene is . The ratio of C to H in it is 6:6 that could be simplified to 1:1. So, an empirical formula of benzene is CH.
In the first pair, the ratio of C to H in first molecule is 2:4 that could be simplified to 1:2 and the empirical formula is . In second molecule the ratio of C to H is 6:6 and it could be simplified to 1:1. and the empirical formula is CH. Empirical formulas are different for both the molecules of first pair and so it is not the right choice.
In second pair, C to H ratio in first molecule is 1:2, so the empirical formula is . The C to H ratio for second molecule is 1:4, so the empirical formula is
. Here also, the empirical formulas are not same and hence it is also not the right choice.
In third pair, C to H ratio in first molecule is 1:3, so the empirical formula is . In second molecule the C to H ratio is 2:6 and it is simplified to 1:3. So, the empirical formula for this one is also
. Hence. this is the correct choice.
In fourth pair, first molecule empirical formula is CH. Second molecule has 2:4 that is 1:2 mole ratio of C to H and so its empirical formula is . As the empirical formulas are different, it is not the right choice.
So, the only and only correct pair is the third one. 3. and
Answer : Electron P has greater energy difference than the Electron N.
Explanation :
Wavelength range of violet light = 400 - 500 nm
Wavelength range of orange light = 600 - 700 nm
The Planck's equation is,
where,
E = energy of light
c = speed of light
= wavelength of light
According to the Planck's equation, wavelength and energy follow inverse relation. As the wavelength increases, energy decreases.
From the given spectrum, the wavelength of violet light is less. We conclude that When electron P gives violet light on transition it means that energy difference between the energy level was high.
From the given spectrum, the wavelength of orange light is more. We conclude that When electron N gives orange light on transition it means that energy difference between the energy level was low.
So, Electron P which gives violet light on transition has greater energy difference than the Electron N.