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Inessa05 [86]
2 years ago
8

Aqueous sulfuric acid H2SO4 reacts with solid sodium hydroxide NaOH to produce aqueous sodium sulfate Na2SO4 and liquid water H2

O. What is the theoretical yield of sodium sulfate formed from the reaction of 75.5g of sulfuric acid and 105.g of sodium hydroxide
Chemistry
1 answer:
Pie2 years ago
4 0

Answer:

109.34 g

Explanation:

2NaOH(aq) + H2SO4(aq) ------> Na2SO4(aq) + 2H2O(l)

Number of moles of NaOH = 105g/40g/mol = 2.6 moles

From the reaction equation;

2 moles of NaOH yields 1 mole of sodium sulphate

2.6 moles of NaOH yields = 2.6 × 1/2 = 1.3 moles of sodium sulphate

Number of moles of H2SO4= 75.5g/98 g/mol = 0.77 moles

From the reaction equation;

1 mole of H2SO4 yields 1 mole of sodium sulphate

Hence, 0.77 moles of H2SO4 yields 0.77 moles of sodium sulphate

So H2SO4 is the limiting reactant.

Theoretical yield = number of moles × molar mass

= 0.77 mol ×142 g/mol

= 109.34 g

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The question is incomplete, here is the complete question:

While ethanol is produced naturally by fermentation, e.g. in beer- and wine-making, industrially it is synthesized by reacting ethylene with water vapor at elevated temperatures.

A chemical engineer studying this reaction fills a 1.5 L flask at 12°C with 1.8 atm of ethylene gas and 4.7 atm of water vapor. When the mixture has come to equilibrium she determines that it contains 1.16 atm of ethylene gas and 4.06 atm of water vapor.

The engineer then adds another 1.2 atm of ethylene, and allows the mixture to come to equilibrium again. Calculate the pressure of ethanol after equilibrium is reached the second time. Round your answer to 2 significant digits.

<u>Answer:</u> The partial pressure of ethanol after equilibrium is reached the second time is 1.0 atm

<u>Explanation:</u>

We are given:

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Initial partial pressure of water vapor = 4.7 atm

Equilibrium partial pressure of ethylene gas = 1.16 atm

Equilibrium partial pressure of water vapor = 4.06 atm

The chemical equation for the reaction of ethylene gas and water vapor follows:

                     CH_2CH_2(g)+H_2O(g)\rightleftharpoons CH_3CH_2OH(g)

<u>Initial:</u>                  1.8                4.7

<u>At eqllm:</u>           1.8-x             4.7-x

Evaluating the value of 'x'

\Rightarrow (1.8-x)=1.16\\\\x=0.64

The expression of K_p for above equation follows:

K_p=\frac{p_{CH_3CH_2OH}}{p_{CH_2CH_2}\times p_{H_2O}}

p_{CH_2CH_2}=1.16atm\\p_{H_2O}=4.06atm\\p_{CH_3CH_2OH}=0.64atm

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K_p=\frac{0.64}{1.16\times 4.06}\\\\K_p=0.136

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                     CH_2CH_2(g)+H_2O(g)\rightleftharpoons CH_3CH_2OH(g)

<u>Initial:</u>                2.36             4.06               0.64

<u>At eqllm:</u>           2.36-x        4.06-x             0.64+x

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