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Vlad1618 [11]
3 years ago
9

How much heat is released when 24.8 g of ch4 is burned in excess oxygen gas?

Chemistry
1 answer:
balu736 [363]3 years ago
4 0

The given question is incomplete. The complete question is:

How much heat is produced when 24.8 g of CH_4 is burned in excess oxygen gas

Given: CH _4
+2O_2\rightarrow CO_2+2H_2O  ΔH= −802 kJ.

Answer: 1243.1 kJ

Explanation:

Heat of combustion is the amount of heat released on complete combustion of 1 mole of substance.

Given :

Amount of heat released on combustion of  1 mole of methane = 802 kJ kJ/mol

According to avogadro's law, 1 mole of every substance occupies 22.4 L at NTP, weighs equal to the molecular mass and contains avogadro's number 6.023\times 10^{23} of particles.

1 mole of CH_4 weighs = 16 g  

Thus we can say:  

16 g of CH_4 on combustion releases heat = 802 kJ

Thus 24.8 g of CH_4 on combustion releases =\frac{802}{16}\times 24.8=1243.1kJ

Thus heat released when 24.8 g of methane is burned in excess oxygen gas is 1243.1 kJ

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3 0
2 years ago
How much energy must be removed from a 94.4 g sample of benzene (molar mass= 78.11 g/mol) at 322.0 K to solidify the sample and
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Answer : The energy removed must be, 29.4 kJ

Explanation :

The process involved in this problem are :

(1):C_6H_6(l)(322K)\rightarrow C_6H_6(l)(279K)\\\\(2):C_6H_6(l)(279K)\rightarrow C_6H_6(s)(279K)\\\\(3):C_6H_6(s)(279K)\rightarrow C_6H_6(s)(205K)

The expression used will be:  

Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]

where,

Q = heat released for the reaction = ?

m = mass of benzene = 94.4 g

c_{p,s} = specific heat of solid benzene = 1.51J/g^oC=1.51J/g.K

c_{p,l} = specific heat of liquid benzene = 1.73J/g^oC=1.73J/g.K

\Delta H_{fusion} = enthalpy change for fusion = -9.8kJ/mol=-\frac{9.8\times 1000J/mol}{78g/mol}=-125.6J/g

Now put all the given values in the above expression, we get:

Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]

Q=-29427.312J=-29.4kJ

Negative sign indicates that the heat is removed from the system.

Therefore, the energy removed must be, 29.4 kJ

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