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ANTONII [103]
3 years ago
9

The weak ionization constant (Ka) for HCN is equal to:

Chemistry
1 answer:
denis-greek [22]3 years ago
3 0

Answer:

Ka = [H⁺] × [CN⁻] / [HCN]

Explanation:

Cyanhydric acid is a weak acid, according to the following equation:

HCN(aq) ⇄ H⁺(aq) + CN⁻(aq)

The acid ionization constant (Ka) is equal to the product of the concentrations of the ions raised to the stoichiometric coefficients divided by the concentration of the undissociated acid raised to its stoichiometric coefficient.

Ka for HCN is:

Ka = [H⁺] × [CN⁻] / [HCN]

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Answer:

\delta H_{rxn} = -66.0  \ kJ/mole

Explanation:

Given that:

3FeO_3_{(s)}+CO_{(g)} \to 2Fe_3O_4_{(s)} +CO_{2(g)} \  \ \delta H = -47.0 \ kJ/mole  -- equation (1)  \\ \\ \\ Fe_2O_3_{(s)} +3CO_{(g)} \to 2FE_{(s)} + 3CO_{2(g)}  \ \ \delta H = -25.0 \ kJ/mole  -- equation (2)  \\ \\ \\ Fe_3O_4_{(s)} + CO_{(g)} \to 3FeO_{(s)} + CO_{2(g)} \ \delta H = 19.0 \ kJ/mole  -- equation (3)

From equation (3) , multiplying (-1) with equation (3) and interchanging reactant with the product side; we have:

3FeO_{(s)} + CO_{2(g)}    \to    Fe_3O_4_{(s)} + CO_{(g)}   \ \delta H = -19.0 \ kJ/mole  -- equation (4)

Multiplying  (2) with equation (4) ; we have:

6FeO_{(s)} + 2CO_{2(g)}    \to    2Fe_3O_4_{(s)} + 2CO_{(g)}   \ \delta H = -38.0 \ kJ/mole  -- equation (5)

From equation (1) ; multiplying (-1) with equation (1); we have:

2Fe_3O_4_{(s)} +CO_{2(g)} \to     3FeO_3_{(s)}+CO_{(g)}   \  \ \delta H = 47.0 \ kJ/mole  -- equation (6)

From equation (2); multiplying (3) with equation (2); we have:

3 Fe_2O_3_{(s)} +9CO_{(g)} \to 6FE_{(s)} + 9CO_{2(g)}  \ \ \delta H = -75.0 \ kJ/mole  -- equation (7)

Now; Adding up equation (5), (6) & (7) ; we get:

6FeO_{(s)} + 2CO_{2(g)}    \to    2Fe_3O_4_{(s)} + 2CO_{(g)}   \ \delta H = -38.0 \ kJ/mole  -- equation (5)

2Fe_3O_4_{(s)} +CO_{2(g)} \to     3FeO_3_{(s)}+CO_{(g)}   \  \ \delta H = 47.0 \ kJ/mole  -- equation (6)

3 Fe_2O_3_{(s)} +9CO_{(g)} \to 6FE_{(s)} + 9CO_{2(g)}  \ \ \delta H = -75.0 \ kJ/mole  -- equation (7)

<u>                                                                                                                      </u>

FeO  \ \ \ +  \ \ \ CO   \ \  \to   \ \ \ \ Fe_{(s)} + \ \ CO_{2(g)} \ \ \  \delta H = - 66.0 \ kJ/mole

<u>                                                                                                                     </u>

<u />

\delta H_{rxn} = \delta H_1 +  \delta H_2 +  \delta H_3    (According to Hess Law)

\delta H_{rxn} = (-38.0 +  47.0 + (-75.0)) \ kJ/mole

\delta H_{rxn} = -66.0  \ kJ/mole

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ANSWER

EXPLANATION

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\Delta E\text{ }=\text{ q }+\text{ w}

Since heat is released to the surrounding, then q = -12J

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Hence, w = -4.2J

Step 2; Substitute the given data into the formula in step 1

\begin{gathered} \text{  }\Delta E\text{ = q + w} \\ \text{  }\Delta E\text{ }=\text{ -12.4 }+\text{ \lparen-4.2\rparen} \\ \text{  }\Delta E\text{ = -12.4 - 4.2} \\ \text{  }\Delta E\text{ }=\text{ -16.6J} \end{gathered}

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