Answer:
Part A is just T2 = 58.3 K
Part B ∆U = 10967.6 x C
You can work out C
Part C
Part D
Part E
Part F
Explanation:
P = n (RT/V)
V = (nR/P) T
P1V1 = P2V2
P1/T1 = P2/T2
V1/T1 = V2/T2
P = Pressure(atm)
n = Moles
T = Temperature(K)
V = Volume(L)
R = 8.314 Joule or 0.08206 L·atm·mol−1·K−1.
bar = 0.986923 atm
N = 14g/mol
N2 Molar Mass 28g
n = 3.5 mol N2
T1 = 350K
P1 = 1.5 bar = 1.4803845 atm
P2 = 0.25 bar = 0.24673075 atm
Heat Capacity at Constant Volume
Q = nCVΔT
Polyatomic gas: CV = 3R
P = n (RT/V)
0.986923 atm x 1.5 = 3.5 mol x ((0.08206 L atm mol -1 K-1 x 350 K) / V))
V = (nR/P) T
V = ((3.5 mol x 0.08206 L atm mol -1 K-1)/(1.5 x 0.986923 atm) )x 350K
V = (0.28721/1.4803845) x 350
V = 0.194 x 350
V = 67.9036 L
So V1 = 67.9036 L
P1V1 = P2V2
1.4803845 atm x 67.9036 L = 0.24673075 x V2
100.52343693 = 0.24673075 x V2
V2 = P1V1/P2
V2 = 100.52343693/0.24673075
V2 = 407.4216 L
P1/T1 = P2/T2
1.4803845 atm / 350 K = 0.24673075 atm / T2
0.00422967 = 0.24673075 /T2
T2 = 0.24673075/0.00422967
T2 = 58.3 K
∆U= nC
∆T
Polyatomic gas: C
= 3R
∆U= nC
∆T
∆U= 28g x C
x (350K - 58.3K)
∆U = 28C
x 291.7
∆U = 10967.6 x C
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Answer:
Democritus
Explanation:
He spoke about matter was made of tiny particles which moved in empty space
Answer:
See explanation.
Explanation:
Since potassium tert-butoxide is a strong bulky base, we expect that an elimination reaction predominates.
This reaction is expected to occur by E2 mechanism. The cis isomer of 1-bromo-4-tert-butylcyclohexane is known to react faster by E2 mechanism because it fulfills the anticoplanar arrangement required for for E2 mechanism, where the leaving group and adjacent proton must be anti to each other and in the same plane. The trans isomer can not fulfill this requirement.