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tamaranim1 [39]
3 years ago
7

Alkanes react with nitric acid to give what?​

Chemistry
1 answer:
Anna007 [38]3 years ago
4 0

Answer:

<em>The polyoxometalates initially abstract the hydrogen of the alkane to form the alkyl radical and the reduced polyoxometalates. The reduced polyoxometalates subsequently react with nitric acid to produce the oxidized form and nitrogen dioxide.</em>

Explanation:

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At an elevated temperature, Kp=4.2 x 10^-9 for the reaction 2HBr (g)---&gt; +H2(g) + Br2 (g). If the initial partial pressures o
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Answer : The partial pressure of H_2 at equilibrium is, 1.0 × 10⁻⁶

Explanation :

The partial pressure of HBr = 1.0\times 10^{-2}atm

The partial pressure of H_2 = 2.0\times 10^{-4}atm

The partial pressure of Br_2 = 2.0\times 10^{-4}atm

K_p=4.2\times 10^{-9}

The balanced equilibrium reaction is,

                                2HBr(g)\rightleftharpoons H_2(g)+Br_2(g)

Initial pressure    1.0×10⁻²       2.0×10⁻⁴      2.0×10⁻⁴

At eqm.            (1.0×10⁻²-2p)   (2.0×10⁻⁴+p)  (2.0×10⁻⁴+p)

The expression of equilibrium constant K_p for the reaction will be:

K_p=\frac{(p_{H_2})(p_{Br_2})}{(p_{HBr})^2}

Now put all the values in this expression, we get :

4.2\times 10^{-9}=\frac{(2.0\times 10^{-4}+p)(2.0\times 10^{-4}+p)}{(1.0\times 10^{-2}-2p)^2}

p=-1.99\times 10^{-4}

The partial pressure of H_2 at equilibrium = (2.0×10⁻⁴+(-1.99×10⁻⁴) )= 1.0 × 10⁻⁶

Therefore, the partial pressure of H_2 at equilibrium is, 1.0 × 10⁻⁶

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4 years ago
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