Answer- A
Explanation- Because you have to look at the symbols and remember which symbol goes with each chemical, if you don't then you could get confused.
According to ideal gas equation, we know for 1 mole of gas: PV=RT
where P = pressure, T = temperature, R = gas constant, V= volume
If '1' and '2' indicates initial and final experimental conditions, we have

Given that: V1 = 100.0 kPa, T1 = 100.0 K, V1 = 2.0 m3, T2 = 400 K, P2 = 200.0 kPa
∴ on rearranging above eq., we get V2 =

∴ V2 = 4 m3
There's no reason, it's just because the sun has a gravitational pull