Answer:
The answer to the question is
The rate constant for the reaction is 1.056×10⁻³ M/s
Explanation:
To solve the question, e note that
For a zero order reaction, the rate law is given by
[A] = -k×t + [A]₀
This can be represented by the linear equation y = mx + c
Such that y = [A], m which is the gradient is = -k, and the intercept c = [A]₀
Therefore the rate constant k which is the gradient is given by
Gradient = ![\frac{[A]_{2} - [A]_{1} }{t_{2} - t_{1} }](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5D_%7B2%7D%20-%20%5BA%5D_%7B1%7D%20%20%7D%7Bt_%7B2%7D%20-%20t_%7B1%7D%20%20%7D)
where [A]₁ = 8.10×10⁻² M and [A]₂ = 1.80×10⁻³ M
= 
= -0.001056 M/s = -1.056×10⁻³ M/s
Threfore k = 1.056×10⁻³ M/s
Mg + 1/2 O2 → MgO
1 mol = 24 g of Mg
X mol = 12 g of Mg
x = 0.5 moles of Mg
Mg :MgO = 1:1 (coefficient from equations using mole ratio)
So
0.5 moles of MgO
1 mol MgO = (24+16) g = 40 g
0.5 moles of MgO = 0.5 × 40
= 20 g of MgO produced
Answer: The last electron will be filled in first orbital of 3p sub-shell.
Explanation: Filling of electrons in orbitals is done by using Hund's Rule.
Hund's rule states that the electron will be singly occupied in the orbital of the sub-shell before any orbital is doubly occupied.
For filling up of the electrons in Sulfur atom having 16 electrons. First 10 electrons will completely fill according to Aufbau's Rule in 1s, 2s and 2p sub-shells and last 6 electrons are the valence electrons which will be filled in the order of 3s and then 3p.
3s sub-shell will be fully filled and the orbitals of 3p sub-shell will be first singly occupied and then pairing will take place. Hence, the last electron will be filled in the first orbital of 3p-sub-shell.
Use the ideal gas law:
PV = nRT
so, T = PV / nR
n=0.5
V= 120 dm^3 = 120 L (1 dm^3 = 1 L)
R = 1/12
P = 15,000 Pa = 0.147 atm (1 pa = 9.86 10^{-6} )
Put the values:
T = PV / nR
T = (0.147) (120) / (0.5) (1/12)
T= 426 K
Answer:
Explanation:
The polarity of the 3 compounds would be in the order of
Ferrocene < Acetylferrocene < Diacetylferrocene
Your TLC data has to also support this observation . This can be checked by measuring the values of Rf ( Retention factor = distance travelled by solute/solvent ) .The Rf values also has to follow this particular order: -
Ferrocene > acetylferrocene > diacetylferrocene
2) Hexane happens to be a non-polar solvent. The polarity of hexane can be increased if some polar solvents for example, ethyl and methylene chloride etc are added
Therefore, in the increasing order of solvents polarity, we have
Hexane < 1:1 mixture of hexane: methylene chloride < 9:1 mixture of methylene chloride:
3) Chromatographic techniques all have a stationary phase in addition to a mobile phase. In the case of column chromatography, the silica gel will be the stationary phase and the solvent that will be poured will be the mobile phase.
4) The TLC and column chromatography both happen to have the same stationary phase which is the silica gel. Also, the same solvent mixture is used in both the techniques. This makes the result of the 2 to be almost the same. The difference seen between them is that, TLC works against the gravity while on the other hand column chromatography works in the direction of the gravity.
5) The key feature in the IR spectra of the acetylferrocene that will be absent in the spectra of ferrocene is the presence of carbonyl stretching frequency at close to 1700 per cm(cm-1). This peak is easily differentiated between both acetyl ferrocene and ferrocene.
