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drek231 [11]
3 years ago
5

Realiza los cálculos para determinar la cantidad de KOH 90%, que se necesita para preparar 100 ml de solución 1N.

Chemistry
1 answer:
attashe74 [19]3 years ago
8 0

Answer:

6.23 KOH 90% son necesarios

Explanation:

Una solución 1N de KOH requiere 1equivalente (En KOH, 1eq = 1mol) por cada litro de solución.

Para responder esta pregunta se requiere hallar los equivalentes = Moles de KOH para preparar 100mL = 0.100L de una solución 1N. Haciendo uso de la masa molar de KOH y del porcentaje de pureza del KOH se pueden calcular los gramos requeridos para preparar la solución así:

<em>Equivalentes KOH:</em>

0.100L * (1eq / L) = 0.100eq = 0.100moles

<em>Gramos KOH -Masa molar: 56.1056g/mol-:</em>

0.100moles * (56.1056g/mol) = 5.61 KOH se requieren

<em>KOH 90%:</em>

5.61g KOH * (100g KOH 90% / 90g KOH) =

<h3>6.23 KOH 90% son necesarios</h3>
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A common "rule of thumb" for many reactions around room temperature is that the rate will double for each ten degree increase in temperature. Does the reaction you have studied seem to obey this rule? (Hint: Use your activation energy to calculate the ratio of rate constants at 300 and 310 Kelvin.)

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If we consider the activation energy to be constant for the increase in 10 K temperature. (i.e. 300 K → 310 K), then the rate of the reaction will increase. This happens because of the change in the rate constant that leads to the change in overall rate of reaction.

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$T_1=300 \ K$

$T_2=310 \ K$

The rate constant = $K_1 \text{ and } K_2$ respectively.

The activation energy and the Arhenius factor is same.

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$K_1 = Ae^{-\frac{E_a}{RT_1}}$  and $K_2 = Ae^{-\frac{E_a}{RT_2}}$

$\Rightarrow \frac{K_1}{K_2}= \frac{e^{-\frac{E_a}{RT_1}}}{e^{-\frac{E_a}{RT_2}}} $

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$\Rightarrow \ln \frac{K_1}{K_2}= - \frac{E_a}{R} \left(\frac{1}{T_1} -\frac{1}{T_2} \right)$

$\Rightarrow \ln \frac{K_2}{K_1}=  \frac{E_a}{R} \left(\frac{1}{T_1} -\frac{1}{T_2} \right)$

Given, $E_a = 0.269$ J/mol

           R = 8.314 J/mol/K

$\Rightarrow \ln \frac{K_2}{K_1}=  \frac{0.269}{8.314} \left(\frac{1}{300} -\frac{1}{310} \right)$

$\Rightarrow \ln \frac{K_2}{K_1}=  \frac{0.269}{8.314} \times \frac{10}{300 \times 310}$

$\Rightarrow \ln \frac{K_2}{K_1}=  3.479 \times 10^{-6}$

$\Rightarrow  \frac{K_2}{K_1}=  e^{3.479 \times 10^{-6}}$

$\Rightarrow  \frac{K_2}{K_1}=  1$

∴ $K_2=K_1$

So, no this reaction does not seem to follow the thumb rule as its activation energy is very low.

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