The answer to your question is dependent variable.
Its been a long time since ive done this stuff but this chart used to help me a lot
You have to use the equation PV=nRT.
P=pressure (in this case 1.89x10^3 kPa which equals 18.35677 atm)
1V=volume (in this case 685L)
n=moles (in this case the unknown)
R=gas constant (0.08206 (L atm)/(mol K))
T=temperature (in this case 621 K)
with the given information you can rewrite the ideal gas law equation as n=PV/RT.
n=(18.35677atm x 685L)/(0.08206atmL/molK x 621K)
n=246.8 moles
