Isoelectronic species are ions or elements that have equal number of electrons. From the root word, electron of the word isoelectronic. On the other hand, isotructural species are compounds with the same structures.Hope this answers the question.
Answer : The balanced chemical equation will be:
(i) 
(ii) 
Explanation :
Balanced chemical equation : It is defined as the equation in which total number of individual atoms on the reactant side is equal to the total number of individual atoms on product side.
Part (i):
The balanced chemical equation will be:

This reaction is a single displacement reaction in which most reactive element (potassium) displaces the least reactive element (hydrogen) form their solution.
Part (ii):
The balanced chemical equation will be:

This reaction is a single displacement reaction in which most reactive element (zinc) displaces the least reactive element (magnesium) form their solution.
Conduction
In metals, the electrons of each atom are delocalized, which means they are free to move about in the structure of the metal. When heat is applied at one end of the metal, the electrons there are excited and collide with surrounding particles, transferring their energy to them. This is what makes metals very good conductors of both heat and electricity.
A is a model of a decomposition reaction