Answer:
a. Kp=1.4
b.Kp=2.0 * 10^-4
c.Kp=2.0 * 10^5
Explanation:
For the reaction
A(g)⇌2B(g)
Kp is defined as:
The conditions in the system are:
A B
initial 0 1 atm
equilibrium x 1atm-2x
At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.
Replacing these values in the expression for Kp we get:
Working with this equation:
This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1
The general expression to solve these kinds of equations is:
(equation 1)
We just take the positive values from the solution since negative partial pressures don´t make physical sense.
Kp = 1.4
With x1 we get a partial pressure of:
Since negative partial pressure don´t make physical sense x1 is not the solution for the system.
With x2 we get:
These partial pressures make sense so x2 is the solution for the equation.
We follow the same analysis for the other values of Kp.
Kp=2*10^-4
X1=0.505
X2=0.495
With x1
Not sense.
With x2
X2 is the solution for this equation.
Kp=2*10^5
X1=50001
With x1
Not sense.
With x2
X2 is the solution for this equation.
Rutherford theorized that atoms have their charge concentrated in a very small nucleus.
This was famous Rutherford's Gold Foil Experiment: he bombarded thin foil of gold with positive alpha particles (helium atom particles, consist of two protons and two neutrons).
Rutherford observed the deflection of alpha particles on the photographic film and notice that most of alpha particles passed straight through foil.
That is different from Plum Pudding model, because it shows that most of the atom is empty space.
According to Rutherford model of the atom:
1) Atoms have their charge concentrated in a very small nucleus.
2) Major space in an atom is empty.
3) Atoms nucleus is surrounded by negatively charged particles called electrons.
4) An atom is electrically neutral.
I remember coming across this question and the options were:
KOH, HCN, NH₃, HI, Sr(OH)₂
Now, a substance with a low pH is one that dissociates completely in water to release hydrogen ions, while basic substances dissociate completely to release hydroxide ions. Therefore, in the order of increasing pH:
HI, HCN, NH₃, Sr(OH)₂, KOH
Answer:
450. g of 0.173 % KCN solution contains 779 mg of KCN.
Explanation:
Mass of the solution = m
Mass of the KCN in solution = 779 mg
Mass by mass percentage of KCN solution = 0.173%
1 mg = 0.001 g
m = 450,289 mg × 0.001 g = 450.289 mg ≈ 450. g
450. g of 0.173 % KCN solution contains 779 mg of KCN.