6. Calculate the mass of each product when 100.0 g of CuCl react according to the reaction
1 answer:
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The question is missing the molecules in which the integration ratio of 2:3 will be observed. The complete question is given in the attachment.
Answer:
Molecule (a), (c), and (f) will show two peaks with the integration ratio of 2:3 in their 1H NMR spectrum
Explanation:
In the 1H NMR spectrum, the peak area is dependent on the number of hydrogen in a specific chemical environment. Hence, the ratio of the integration of these signals provides us with the relative number of hydrogen in two peaks. This rationale is used for the assignment of molecules that will give 2:3 integration ratio in the given problem.
- Molecule (a) have two CH₂ and three CH₃ groups. Hence, it will give two peaks and their integration ratio becomes 2:3 (Answer)
- Molecule (b) contains three chemical environments for its hydrogen atoms
- Molecule (c) have a single CH₂ and CH₃ group giving integration ratio of 2:3 (Answer)
- Molecule (d) will give two peaks but their ratio will be 1:3 because of two hydrogens of CH₂ and six hydrogens from two CH₃ groups
- Molecule (e) have three CH and three CH₃ groups, so their ratio will become 1:3
- Molecule (f) contains four CH and two CH₃ groups, giving two peaks. So, the integration ratio of their peaks is 2:3 (Answer)
- Molecules
- (g)
- and
- (h)
- both have two CH and two CH₃ groups giving two peaks with the integration ratio of 1:3
Answer:
The answer to this can be arrived at by clculating the mole fraction of atoms higher than the activation energy of 10.0 kJ by pluging in the values given into the Arrhenius equation. The answer to this is 20.22 moles of Argon have energy equal to or greater than 10.0 kJ
Explanation:
From Arrhenius equation showing the temperature dependence of reaction rates.
where
k = rate constant
A = Frequency or pre-exponential factor
Ea = energy of activation
R = The universal gas constant
T = Kelvin absolute temperature
we have
Where
f = fraction of collision with energy higher than the activation energy
Ea = activation energy = 10.0kJ = 10000J
R = universal gas constant = 8.31 J/mol.K
T = Absolute temperature in Kelvin = 400K
In the Arrhenius equation k = Ae^(-Ea/RT), the factor A is the frequency factor and the component e^(-Ea/RT) is the portion of possible collisions with high enough energy for a reaction to occur at the a specified temperature
Plugging in the values into the equation relating f to activation energy we get
or f =
= 20.22 moles of argon have an energy of 10.0 kJ or greater