Answer:
Keq = 0.053
7.3 kJ/mol
Explanation:
Let's consider the following isomerization reaction.
glucose 6‑phosphate ⇄ glucose 1 - phosphate
The concentrations at equilibrium are:
[G6P] = 0.19 M
[G1P] = 0.01 M
The concentration equilibrium constant (Keq) is:
Keq = [G1P] / [G6P]
Keq = 0.01 / 0.19
Keq = 0.053
We can find the standard free energy change, ΔG°, of the reaction mixture using the following expression.
ΔG° = -R × T × lnKeq
ΔG° = -8.314 J/mol.K × 298 K × ln0.053
ΔG° = 7.3 × 10³ J/mol = 7.3 kJ/mol
To calculate the pKa of the weak acid, we use the Henderson-Hasselbalch equation. It is expressed as pH = pKa - log [HA]/[A-]. This equation takes into account the concentration of the substance that does not dissociates into ions since it is a weak acid. We caculate as follows:
pH = pKa - log [HA]/[A-]
9 = pKa - log 1/100
pKa = 7
They are about 4.5 billion years old. Hope this helps.
½H2(g) + ½I2(g) → HI(g) ΔH = +6.2 kcal/mol
or...
½H2(g) + ½I2(g) + 6,2kcal/mole → HI(g)
________
21.0 kcal/mole + C(s) + 2S(s) → CS2(l)
or...
C(s) + 2S(s) → CS2(l) ΔH = +2,1 kcal/mole
_________
ΔH > 0 ----------->>> ENDOTHERMIC REACTIONS
