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Evgen [1.6K]
3 years ago
6

Give the product of the reaction of excess benzene (2 equivalents) with dichloromethane and alcl3.

Chemistry
1 answer:
SOVA2 [1]3 years ago
5 0
Hello!

The product of the reaction of excess benzene with dichloromethane is diphenylmethane. 

The reaction that benzene undergoes with dichloromethane is a Friedel-Crafts Alkylation, in which firstly Benzene is alkylated to Benzyl Chloride, and after that, the Benzyl Chloride reacts with another equivalent of Benzene to form the compound Diphenylmethane. The Reaction Scheme is shown in the image below:

Have a nice day!

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Answer: Number of molecules of hydrogen gas 6.32\times 10^{32}

Explanation:

2Na+2H_2O\rightarrow 2NaOH+H_2

Number of moles of sodium =\frac{\text{mass of sodium}}{\text{molar mass of sodium}}=\frac{48.7 g}{23 g/mol}=2.11mol

According to reaction , 2 moles of sodium produces 1 mole of hydrogen gas , then 2.11 mol of sodium will= \frac{1}{2}\times 2.11 mol of hydrogen gas that is 1.05 moles of hydrogen gas.

Number of molecules = N_A(\text{Avogadro number})\times moles of substance

Moles of hydrogen gas formed = 1.05 moles

Number of molecules of hydrogen gas = N_A\times moles of hydrogen gas

Number of molecules of hydrogen gas =6.022\times 10^{23} mole^{-1}\times 1.05 mole=6.32\times 10^{32}

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Dissolution of KOH, ΔHsoln:
swat32

Using Hess's law we found:

1) By <em>adding </em>reaction 10.2 with the <em>reverse </em>of reaction 10.1 we get reaction 10.3:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)   ΔH  (10.3)

2) The ΔHsoln must be subtracted from ΔHneut to get the <em>total </em>change in enthalpy (ΔH).    

The reactions of dissolution (10.1) and neutralization (10.2) are:

KOH(s) → KOH(aq)   ΔHsoln    (10.1)

KOH(s) + HCl(aq) → H₂O(l) + KCl(aq)     ΔHneut     (10.2)

1) According to Hess's law, the total change in enthalpy of a reaction resulting from <u>differents changes</u> in various <em>reactions </em>can be calculated as the <u>sum</u> of all the <em>enthalpies</em> of all those <em>reactions</em>.      

Hence, to get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq)    (10.3)

We need to <em>add </em>reaction 10.2 to the <u>reverse</u> of reaction 10.1

KOH(s) + HCl(aq) + KOH(aq) → H₂O(l) + KCl(aq) + KOH(s)

<u>Canceling</u> the KOH(s) from both sides, we get <em>reaction 10.3</em>:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)    (10.3)

2) The change in enthalpy for <em>reaction 10.3</em> can be calculated as the sum of the enthalpies ΔHsoln and ΔHneut:

\Delta H = \Delta H_{soln} + \Delta H_{neut}

The enthalpy of <em>reaction 10.1 </em>(ΔHsoln) changed its sign when we reversed reaction 10.1, so:

\Delta H = \Delta H_{neut} - \Delta H_{soln}

Therefore, the ΔHsoln must be <u>subtracted</u> from ΔHneut to get the total change in enthalpy ΔH.

Learn more here:

  • brainly.com/question/2082986?referrer=searchResults
  • brainly.com/question/1657608?referrer=searchResults  

I hope it helps you!

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