How many Joules are present in 7401 kJ?

The equilibrium constant in terms of pressure. Kp for the following process is 0.179 at 50 °C. It increases to 0.669 at 86 °C. C

Vikentia [17]

Answer:

a) ΔHvap=35.3395 kJ/mol

b) Tb=98.62 °C

Explanation:

Given the reaction:

C₇H₁₆ (l) ⇔ C₇H₁₆ (g)

Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.

When

T₁=50°C=323.15K ⇒P₁=0.179

T₂=86°C=359.15K ⇒P₂=0.669

The Clasius-Clapeyron equation is:

$ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})$

$ln(\frac{0.669}{0.179}) =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{359.15K}-\frac{1}{323.15K})$

$1.3184 =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (-3.10186*10^{-4}K{^-1})$

ΔHvap=35339.5 J/mol=35.3395 KJ/mol

Normal boiling point ⇒ P=1 atm

Hence, we find the normal boiling point where:

T₁=323.15K

P₁=0.179 atm

P₂=1 atm

$ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})$

$ln(\frac{1atm}{0.179atm}) =-\frac{35339.5 J/mol}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{T_2}-\frac{1}{323.15K})$

$1.7203=-4250.34 (\frac{1}{T_2}-\frac{1}{323.15K})$

T₂=371.77 K= 98.62 °C

5 0

2 years ago

write equations to show the chemical processes which occur when the first ionization and the second ionization energies of lithi

diamong [38]

Answer:

First ionization of lithium:

$\text{Li}\;(g)\to \text{Li}^{+} \; (g) + \text{e}^{-}$ .

Second ionization of lithium:

$\text{Li}^{+}\;(g) \to\text{Li}^{2+} \;(g) + \text{e}^{-}$ .

Explanation:

The ionization energy of an element is the energy required to remove the outermost electron from an atom or ion of the element in gaseous state. (Refer to your textbook for a more precise definition.) Some features of the equation:

Start with a gaseous atom (for the first ionization energy only) or a gaseous ion. Write the gaseous state symbol $(g)$ next to any atom or ion in the equation.
The product shall contain one gaseous ion and one electron. The charge on the ion shall be the same as the order of the ionization energy. For the second ionization energy, the ion shall carry a charge of +2.
Charge shall balance on the two sides of the equation.

First Ionization Energy of Li:

The products shall contain a gaseous ion with charge +1 $\text{Li}^{+}\;(g)$ as well as an electron $\text{e}^{-}$ .
Charge shall balance on the two sides. There's no net charge on the product side. Neither shall there be a charge on the reactant side. The only reactant shall be a lithium atom which is both gaseous and neutral: $\text{Li}\;(g)$ .

Hence the equation: $\text{Li}\;(g) \to \text{Li}^{+}\;(g) + \text{e}^{-}$ .

Second Ionization Energy of Li:

The product shall contain a gaseous ion with charge +2: $\text{Li}^{2+}\;(g)$ as well as an electron $\text{e}^{-}$ .
Charge shall balance on the two sides. What's the net charge on the product side? That shall also be the charge on the reactant side. What will be the reactant?

The equation for this process is $\text{Li}^{+} \; (g) \to \text{Li}^{2+}\;(g) + \text{e}^{-}$ .

5 0

3 years ago

Why do the protons identify the element and not the electrons or the neutrons?

Lunna [17]

Protons identity the element because the number of protons gives us the atomic number of each element

4 0

1 year ago

Which properties do not change the composition of a substance?

Nina [5.8K]

Answer:

Physical Properties

Explanation:

PHYSICAL PROPERTY

7 0

3 years ago

Which substance is a mixture? table salt gasoline aluminum carbon dioxide

GaryK [48]

Answer:

Gasoline

Explanation:

Pure Substance: are those having same type of atoms or molecules.

Compound: one or more atoms of the element combine to form a compound.

Mixture: is combination of one or more substances mix together.

Homogeneous Mixture: are those which are not distinguish by naked eye but can be separated into its components by physical means

Heterogeneous mixture: are those which can be distinguishing by naked eye and can be separated into its components by physical means.

So keeping in mind the above definitions

Table salt:

The chemical formula of table salt is NaCl and it a pure compound not mixture.

Gasoline:

Gasoline is mixture of hydrocarbon, It contains small hydrocarbons ranging from 4 Carbon to 12 Carbon per molecule. it is a homogeneous mixture.

Aluminum:

Aluminum is a pure substance that is made up of same kind of atoms. so it is an element and not mixture. Its symbol is Al

Carbon dioxide:

Carbon dioxide is a pure compound and its chemical formula is CO₂ and not a mixture.

So, the write option is Gasoline.

6 0

3 years ago

Read 2 more answers