Answer:

Explanation:
1. Solubility of CaF_2
(a) Molar solubility
CaF₂ ⇌ Ca²⁺ + 2F⁻
![K_{\text{sp }} = \text{[Ca$^{2+}$]}\text{[F$^{-}$]}^{2}= 4.0 \times 10^{-8}\\s(2s)^{2}=4.0 \times 10^{-8}\\4s^{3} = 4.0 \times 10^{-8}\\s^{3} = 1.0 \times 10^{-8}\\s =2.2 \times 10^{-3}\text{ mol/L}](https://tex.z-dn.net/?f=K_%7B%5Ctext%7Bsp%20%7D%7D%20%3D%20%5Ctext%7B%5BCa%24%5E%7B2%2B%7D%24%5D%7D%5Ctext%7B%5BF%24%5E%7B-%7D%24%5D%7D%5E%7B2%7D%3D%204.0%20%5Ctimes%2010%5E%7B-8%7D%5C%5Cs%282s%29%5E%7B2%7D%3D4.0%20%5Ctimes%2010%5E%7B-8%7D%5C%5C4s%5E%7B3%7D%20%3D%204.0%20%5Ctimes%2010%5E%7B-8%7D%5C%5Cs%5E%7B3%7D%20%3D%201.0%20%5Ctimes%2010%5E%7B-8%7D%5C%5Cs%20%3D2.2%20%5Ctimes%2010%5E%7B-3%7D%5Ctext%7B%20mol%2FL%7D)
(b) Mass solubility

2. pH
pH = -log [H⁺] = -log(3.0 × 10⁻⁴) = 3.52
3. Oxidizing and reducing agents
Zn + Cl₂ ⟶ ZnCl₂

The oxidation number of Cl has decreased from 0 to -1.
Cl has been reduced, so Cl is the oxidizing agent.
4. Oxidation numbers
(a) Al₂O₃

1O = -2; 3O = -6; 2Al = +6; 1Al = +3
(b) XeF₄

1F = -1; 4F = -4; 1 Xe = +4
(c) K₂Cr₂O₇

1K = +1; 2K = +2; 1O = -2; 7O = -14
+2 - 14 = -12
2Cr = + 12; 1 Cr = +6
Can you attach the following concept map on chemical reactions?
Answer:
31.36 Liters
Explanation:
1 mole is equal to 22.4 liters at STP so you can use the equation
1.4 moles * 22.4 liters
to find the volume.
Answer:
37 mmol of acetate need to add to this solution.
Explanation:
Acetic acid is an weak acid. According to Henderson-Hasselbalch equation for a buffer consist of weak acid (acetic acid) and its conjugate base (acetate)-
![pH=pK_{a}(acetic acid)+log[\frac{mmol of CH_{3}COO^{-}}{mmol of CH_{3}COOH }]](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%28acetic%20acid%29%2Blog%5B%5Cfrac%7Bmmol%20of%20CH_%7B3%7DCOO%5E%7B-%7D%7D%7Bmmol%20of%20CH_%7B3%7DCOOH%20%7D%5D)
Here pH is 5.31,
(acetic acid) is 4.74 and number of mmol of acetic acid is 10 mmol.
Plug in all the values in the above equation:
![5.31=4.74+log[\frac{mmol of CH_{3}COO^{-}}{10}]](https://tex.z-dn.net/?f=5.31%3D4.74%2Blog%5B%5Cfrac%7Bmmol%20of%20CH_%7B3%7DCOO%5E%7B-%7D%7D%7B10%7D%5D)
or, mmol of
= 37
So 37 mmol of acetate need to add to this solution.