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Svetach [21]
3 years ago
11

The three beakers shown below contain solutions of [cof6]3–, [co(nh3)6]3+, and [co(cn)6]3–. based on the colors of the three sol

utions, which compound is present in each of the beakers?
Chemistry
1 answer:
vitfil [10]3 years ago
3 0
[Co(CN)₆]³⁻ → Yellow
[Co(NH₃)₆]³⁺ → Orange
[CoF₆]³⁻ → Blue
Explanation:
- All the given compounds have octahedral geometry but the ligand in each are different with the same metal ion.

- Ligands strength order:     CN⁻ > NH₃ > F⁻ 

- The ligand CN will act as a strong field ligand so that the splitting is maximum when compared to NH₃ and F⁻

- If the splitting is more, the energy required for transition is more, and the wavelength is inversely proportional to energy.

- So CN complex will absorb at lower wavelength (yellow color)
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Balance the equation first.

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