Answer: when reactants and products are gases at STP.
Justification:
1) STP stands for standard temperature (0°) and pressure (1 atm).
2) According to the kinetic molecular theory of the gases, and as per Avogadro's principle, equal volumes of gases, at the same temperature and pressure, have the same number of molecules.
3) Since the coefficients in a balanced chemical equation represent number of moles, when reactants and products are gases at the same temperature and pressure, the mole ratios are the same that the volume ratios, and then the coefficients of the chemical equation represent the volume ratios.
Answer : The correct option is, (a) Synthesis
Explanation :
Synthesis reaction : A chemical reaction where multiple substances or reactants combine to form a single product.
It is represented as,

Combustion reaction : A chemical reaction in which a hydrocarbon react with the oxygen to give product as carbon dioxide and water.
It is represented as,

Single replacement reaction : A chemical reaction in which the more reactive element replace the less reactive element.
It is represented as,

In this reaction, A is more reactive element and B is less reactive element.
Double replacement reaction : It is a type of chemical reaction where a positive cation and a negative anion of two reactants exchange places to form two new products.
It is represented as,

(X and A are the cations, Y and B are the anions)
The given reaction is, 
In this reaction, calcium combine with the chloride to form calcium chloride as a product.
Hence, the given type of reaction is a synthesis reaction.
Answer:
E = 12.92 × 10^(-16) J
Explanation:
Formula for energy is;
E = hc/λ
Where;
h is Planck's constant = 6.63 x 10^(-34) J.s
c is speed of light = 3 × 10^(8) m/s
λ is wavelength = 0.154 nm = 0.154 × 10^(-9) m
E = (6.63 x 10^(-34) × 3 × 10^(8))/(0.154 × 10^(-9))
E = 12.92 × 10^(-16) J