Answer:
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
Explanation:
CH4(g) + 2H2O(g) ⇆ CO2(g) + 4H2(g)
CH4(g) H2O(g) CO2(g) H2(g) ΔH°f (kJ/mol): –74.87 –241.8 –393.5 0
ΔG°f (kJ/mol): –50.81 –228.6 –394.4 0
S°(J/K·mol): 186.1 188.8 213.7 130.7
ΔG<0 to be spontaneous
ΔG = ΔH- TΔS <0
ΔH = ∑nΔH(products) - ∑nΔH(reactant)
ΔH = (-393.5) - (–74.87 + 2*–241.8)
ΔH = 164.97 kJ = 164970 J
ΔS = ∑nΔS(products) - ∑nΔS(reactant)
ΔS = (213.7 + 4*130.7) - (186.1 + 2*188.8)
ΔS = 172.8 J
0 > 164970 J - T* 172.8 J
-164970 J > - T* 172.8 J
954.7< T
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
The chemical equilibrium will shift to the left.
Since NH4+ ions are a product of the original reaction, increasing their concentration will shift the equilibrium toward the reactants.
The phrase that describes a characteristic of an Arrhenius base is that Arrhenius base add hydroxide ions to the solution ( answer C)
<u><em>Explanation</em></u>
Arrhenius base is a substance that increases the concentration of OH- in aqueous solution.
The Common Arrhenius base are group 1 and 2 hydroxide such as LiOH, NaOH , Ba(OH)2 among others.
for example NaOH dissociate as follows , NaOH → Na+(aq) + OH- (aq)
Double replacement.
Ba(OH)2 + H2SO4 ====> 2H2O + BaSO4
Answer:
CH3CHO+H2O → CH3OCH3 - addition
CH,CICH CI + Zn → C2H4 + ZnCl2 - elimination
CH3CH3Br + OH – CH3CH3OH + Br - substitution
2CH2COOH >>(CH3CO)20 + H20 - condensation
Explanation:
An addition reaction is a reaction in which a specie is added across the double bond as we can see in CH3CHO+H2O → CH3OCH3.
In an elimination reaction, a small molecule is lost from a saturated compound to form the corresponding unsaturated compound as in CH,CICH CI + Zn → C2H4 + ZnCl2
In a substitution reaction, a chemical moiety replaces another in a molecule as in; CH3CH3Br + OH – CH3CH3OH + Br .
A condensation reaction is in which two molecules are joined together to form a bigger molecule as in; 2CH2COOH >>(CH3CO)20 + H20.
