Answer:
a. 750Hz, b. 4.0ppm, c. 600Hz
Explanation:
The Downfield Shift (Hz) is given by the formula
Downfield Shift (Hz) = Chemical Shift (ppm) x Spectrometer Frequency (Hz)
Using the above formula we can solve all three parts easily
a. fspec = 300 MHz, Chem. Shift = 2.5ppm, 1MHz = 10⁶ Hz, 1ppm (parts per million) = 10⁻⁶
Downfield Shift (Hz) = 2.5ppm x 300MHz x (1Hz/10⁶MHz) x (10⁻⁶/1ppm)
Downfield Shift = 750 Hz
The signal is at 750Hz Downfield from TMS
b. Downfield Shift = 1200 Hz, Chemical Shift = ?
Chemical Shift = Downfield shift/Spectrometer Frequency
Chemical Shift = (1200Hz/300MHz) x (1ppm/10⁻⁶) = 4.0 ppm
The signal comes at 4.0 ppm
c. Separation of 2ppm, Downfield Shift = ?
Downfield Shift (Hz) = 2(ppm) x 300 (MHz) x (1Hz/10⁶MHz) x (10⁻⁶/1ppm) = 600 Hz
The two peaks are separated by 600Hz
Over the ocean, the temperature rises much slower, because the water evaporates causing the hot molecules to go into the atmosphere, and the overall temperature of the water doesn't increase much, this causes the area without the water to be much hotter.
Answer:
Iron has 5 unpaired electrons in Fe⁺³ state.
Explanation:
Iron having atomic number 26 has following electronic configuration in neutral state.
Fe = 1s², 2s², 2p⁶, 3s², 3p⁶, 4s², 3d⁶
When Iron looses three electrons it attains +3 charge with following electronic configuration.
Fe⁺³ = 1s², 2s², 2p⁶, 3s², 3p⁶, 3d⁵
The five electrons in d-orbital exist in unpaired form as,
3(dz)¹, 3d(xz)¹, 3d(yz)¹, 3d(xy)¹, 3(dx²-y²)¹
