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Dafna11 [192]
2 years ago
7

Carbon NMR spectroscopy produces a spectrum of only carbon-13 nuclei in a sample. The number of carbon signals in the spectrum c

orresponds to the number of ________in the molecule. In most carbon NMR spectra, the carbon signals appear as singlet peaks .
Chemistry
1 answer:
UkoKoshka [18]2 years ago
6 0

Answer:

carbons that are in different environments

Explanation:

When molecules are asymmetric every carbon will have its own peak since they are all different and will show up with a different ppm shift.  If the molecule has symmetry the carbons that are symmetrical (in the same environment) will have the same ppm shift and will therefore show up as one peak.  

An example of a molecule with symmetry is isopropanol which has 3 carbons but only two carbon peaks since the two methyl groups are symmetrical.

An example of a molecule with no symmetry is 3-Nitroaniline where the groups coming off of the benzene ring makes each of the 6 carbons be in different environments and there for all 6 carbons will have different ppm shifts.  The result is a carbon NMR that has 6 peaks.

I hope this helps.  Let me know if anything is unclear.

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A weak monoprotic acid is titrated with 0.100 MNaOH. It requires 50.0 mL of the NaOH solution to reach the equivalence point. Af
larisa86 [58]

Explanation:

The given reaction is as follows.

        HA(aq) + NaOH (aq) \rightleftharpoons NaA(aq) + H_{2}O(l)

Hence, number of moles of NaOH are as follows.

        n = 0.05 L \times 0.1 M

           = 0.005 mol

After the addition of 25 ml of base, the pH of a solution is 3.62. Hence, moles of NaOH is 25 ml base are as follows.

             n = 0.025 L \times 0.1 M

                = 0.0025 mol

According to ICE table,

         HA(aq) + NaOH (aq) \rightleftharpoons NaA(aq) + H_{2}O(l)

Initial:     0.005 mol   0.0025 mol              0                  0

Change: -0.0025 mol  -0.0025 mol        +0.0025 mol

Equibm:   0.0025 mol    0                         0.0025 mol

Hence, concentrations of HA and NaA are calculated as follows.

          [HA] = \frac{0.0025 mol}{V}

        [NaA] = \frac{0.0025 mol}{V}

       [A^{-}] = [NaA] = \frac{0.0025 mol}{V}

Now, we will calculate the pK_{a} value as follows.

          pH = pK_{a} + log \frac{A^{-}}{HA}

       pK_{a} = pH - log \frac{[A^{-}]}{[HA]}

                  = 3.42 - log \frac{\frac{0.0025 mol}{V}}{\frac{0.0025}{V}}

                  = 3.42

Thus, we can conclude that pK_{a} of the weak acid is 3.42.

           

8 0
3 years ago
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3 years ago
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HELP!!! name two properties of metals
Olenka [21]

Answer:

1) Ductile

2) Malleable

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Explanation:

3 0
2 years ago
Compared with halogens, the alkali metals in the same period has
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Alkali metals have the lowest electronegativities, while halogens have the highest.
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Upon combustion, a 1.3109 g sample of a compound containing only carbon, hydrogen, and oxygen produces 3.2007 g<img src="https:/
Ivenika [448]

Answer:

The answer to your question is:   C₃H₃O  This is my answer.

Explanation:

Data

Sample = 1.3109 g

CxHyOz

CO₂ = 3.2007 g

H₂O = 1.3102 g

Empirical formula = ?

MW CO2 = 44 g

MW H2O = 18 g

For Carbon

                                     44 g -------------------- 12 g

                                     3.2007 g ------------    x

                                      x = (3.2007 x 12) / 44

                                      x = 0.8729 g of Carbon

                                     12 g of C --------------  1 mol

                                     0.8729 g --------------  x

                                     x = (0.8729 x 1) / 12

                                     x = 0.0727 mol of Carbon

For Hydrogen

                                 18 g ---------------------- 1 g

                              1.3102 g -------------------  x

                                   x = (1.3102 x 1) / 18

                                  x = 0.0727 g of Hydrogen                                      

                                  1 g ------------------------ 1 mol

                                  0.0727g ----------------  x

                                  x = (0.0727 x 1)/1

                                  x = 0.0727 mol of Hydrogen

For oxygen

                    g of Oxygen = g of sample - g of Carbon - g of hydrogen

                    g of Oxygen = 1.3109 - 0.8709 - 0.0727

                    g of Oxygen = 0.3673

                                  16 g of Oxygen ------------- 1 mol of O

                                  0.3673 g ---------------------   x

                                   x = (0.3673 x 1)/ 16

                                   x = 0.0230 mol of Oxygen

Divide by the lowest number of moles

Carbon              0.0727 / 0.023  = 3.1  ≈ 3

Hydrogen         0.0727 / 0.023 = 3.1  ≈ 3

Oxygen             0.0230 / 0.023 = 1

                                        C₃H₃O

8 0
3 years ago
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