1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Ronch [10]
4 years ago
13

If PbI2(s) is dissolved in 1.0MNaI(aq) , is the maximum possible concentration of Pb2+(aq) in the solution greater than, less th

an, or equal to the concentration of Pb2+(aq) in the solution in part ( a ) ? Explain.
Chemistry
1 answer:
fredd [130]4 years ago
3 0

Answer:

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

Less than the concentration of Pb2+(aq) in the solution in part ( a )

Explanation:

From the question:

A)

We assume that s to be  the solubility of PbI₂.

The equation of the reaction is given as :

PbI₂(s) ⇌ Pb²⁺(aq) + 2I⁻(aq); Ksp = 7 × 10⁻⁹

 [Pb²⁺] =   s

Then [I⁻] = 2s

K_{sp} =\text{[Pb$^{2+}$][I$^{-}$]}^{2} = s\times (2s)^{2} =  4s^{3}\\s^{3} = \dfrac{K_{sp}}{4}\\\\s =\mathbf{ \sqrt [3]{\dfrac{K_{sp}}{4}}}\\\\\text{The mathematical expressionthat can be used to determine the value of  }\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

B)

The Concentration of Pb²⁺  in water is calculated as :

\mathbf{s =\sqrt [3]{\dfrac{K_{sp}}{4}}}

\mathbf{s =\sqrt [3]{\dfrac{7*10^{-9}}{4}}}

\mathbf{s} =\sqrt[3]{1.75*10^{-9}}

\mathbf{s} =\mathbf{1.21*10^{-3}  \ mol/L }

The Concentration of Pb²⁺  in 1.0 mol·L⁻¹ NaI

\mathbf{PbCl{_2}}  \leftrightharpoons    \ \ \ \ \ \ \  \mathbf{Pb^{2+}}   \ \ \ \  \ +   \ \  \ \ \ \ \ \mathbf{2 I^-}

                             \ \ \ \ \ \ \  \ \   \ \  \ \ \ \ \ \ \  \mathbf0}   \ \ \ \  \ \ \ \ \ \   \ \ \ \ \ \mathbf{1.0}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{+2x}

                            \ \ \ \ \ \ \ \ \ \ \ \ \ \    \ \ \ \ \  \mathbf{+x}   \ \ \ \  \    \ \  \ \ \ \ \ \mathbf{1.0+2x}

The equilibrium constant:

K_{sp} =[Pb^{2+}}][I^-]^2 \\ \\ K_{sp} = s*(1.0*2s)^2 =7*1.0^{-9} \\ \\ s = 7*10^{-9} \ \  m/L

It is now clear that maximum possible concentration of Pb²⁺ in the solution is less than that in the solution in part (A). This happens due to the  common ion effect. The added iodide ion forces the position of equilibrium to shift to the left, reducing the concentration of Pb²⁺.

You might be interested in
What is an electromagnetic wave?
ira [324]
Electromagnetic waves<span> or </span>EM waves<span> are waves that are created as a result of vibrations between an electric field and a magnetic field.</span>
6 0
4 years ago
An inhibitor is added to an enzyme-catalyzed reaction at a concentration of 26.7 μM. The Vmax remains constant at 50.0 μM/s, but
fomenos

Using the Michaelis-Menten equation competitive inhibition, the Inhibition constant, Ki of the inhibitor is 53.4 μM.

<h3>What is the Ki for the inhibitor?</h3>

The Ki of an inhibitor is known as the inhibition constant.

The inhibition is a competitive inhibition as the Vmax is unchanged but Km changes.

Using the Michaelis-Menten equation for inhibition:

  • Kma = Km/(1 + [I]/Ki)

Making Ki subject of the formula:

  • Ki = [I]/{(Kma/Km) - 1}

where:

  • Kma is the apparent Km due to inhibitor
  • Km is the Km of the enzyme-catalyzed reaction
  • [I] is the concentration of the inhibitor

Solving for Ki:

where

[I] = 26.7 μM

Km = 1.0

Kma = (150% × 1 ) + 1 = 2.5

Ki = 26.7 μM/{(2.5/1) - 1)

Ki = 53.4 μM

Therefore, the Inhibition constant, Ki of the inhibitor is 53.4 μM.

Learn more about enzyme inhibition at: brainly.com/question/13618533

5 0
3 years ago
What happens when an atom forms an ion?
Snowcat [4.5K]

Answer:

An is formed when an atom loses or gains one or more electrons. Because the number of electrons in an ion is different from the number of protons, an ion does have an overall electric charge.

Explanation:

4 0
3 years ago
Read 2 more answers
Can yall plz help me it’s a huge major grade and i don’t know how to do this
fomenos

Answer:

1. 48 mols

2. 0.2 M

5. 1.25 L

Explanation:

Molarity= mols divided by liters

Hope this helps not sure about 3 and 4

3 0
4 years ago
What is the difference between a sea and an ocean
IceJOKER [234]

Seas are smaller than oceans. Oceans are where land and water meet, and are usually bigger.

8 0
3 years ago
Other questions:
  • What is the difference between applied and pure chemistry?
    5·1 answer
  • What does the epidermis do for the skin?
    6·1 answer
  • Can i have help? with 1-7?
    5·2 answers
  • Nitrogen dioxide gas is obtained by the reaction of nitrogen monoxide gas and oxygen gas . Write a balanced chemical equation fo
    12·1 answer
  • How have new technologies made it easier for scientists around the world to share ideas with each other?
    10·1 answer
  • Use the balanced equation below to answer the question that follows
    13·1 answer
  • Why does a circuit need to connect the negative to the positive sides of a battery?
    14·1 answer
  • When I cut it a gas will irritate my eye. Sometimes when I'm cooking you might see me cry.
    11·1 answer
  • "Working on rigs is dangerous due to explosions and weather"
    6·2 answers
  • Which of the following is a transition element<br> A)H<br> B) He<br> C) Fr<br> D) Rn<br> E) Rh
    13·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!