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ipn [44]
4 years ago
7

What mass of sodium hydroxide will completely neutralize 2.5 mol of sulfuric acid?

Chemistry
1 answer:
VMariaS [17]4 years ago
7 0

Given :

2.5 mole of Sulfuric acid ( H_2SO_4 ) .

To Find :

Mass of sodium hydroxide will completely neutralize 2.5 mol of sulfuric acid

Solution :

Let us assume volume of water be 1 L .

Now , we know , to neutralize 1 mole of sulfuric acid we need 2 moles of NaOH .

So , for 2.5 mole sulfuric acid required 5 mole of NaOH .

Moles of NaOH ,

n=M\times Volume \\\\n=5\times 1=5\ moles  

Molecular mass of NaOH , M.M = 58.44 g/mol .

Mass of 5 moles of NaOH :

m=5\times 58.44\ g\\\\m=292.2\ g

Hence , this is the required solution .

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8 0
3 years ago
Sulfuryl chloride is in equilibrium with sulfur dioxide and chlorine gas: so2cl2(g) so2(g) + cl2(g) a system with a volume of 1.
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Answer:

Sulfuryl chloride decreases by -1/21 (-4.76%) (option c)

Explanation:

Denoting

sc= so2cl2(g)

s=so2(g)

c=cl2(g)

Assuming that the compression is an isothermal process , then reaction equilibrium constant in terms of pressure does not change

Kp= psc/ps*pc =

where p= partial pressures

Assuming ideal behaviour , then from Dalton's law,

Xsc₁=psc₁/P₁= psc₁/P₁ = 1 bar/(1 bar + 0.1 bar + 0.1 bar) = 5/6

Xs=ps₁/P₁ = 0.1/1.2=1/12

Xc=pc₁/P₁ = 0.1/1.2=1/12

since Xs=Xc → the reaction started as pure Sulfuryl chloride . Then representing ξ as the extent of reaction and n as the moles

nsc=nsc₀*(1-ξsc) , ns=nsc₀*ξsc , nc=nsc₀*ξsc → n=nsc +ns +nc = nsc₀*(1+ξsc)

therefore

Xs₁=ns₁/n₁=ξsc₁/(1+ξsc₁) →  Xs₁*ξsc₁+Xs₁=ξsc₁ → ξsc₁=Xs₁/(1-Xs₁) = (1/12)/(11/12)= 1/11

then from the ideal gas law

ps₁*V₁=ns₁*R*T

after the reduction

ps₂V₂=ns₂*R*T

dividing both equations

(ps₂/ps₁)*(V₂/V₁)=(ns₂/ns₁)=nsc₀*ξsc₂/(nsc₀*ξsc₁) = ξsc₂/ξsc₁

ps₂ = ps₁ * (V₁/V₂) * (ξsc₂/ξsc₁)

since

psc₁*V₁=nsc₁*R*T , psc₂V₂=nsc₂*R*T → psc₂ =  psc₁ * (V₁/V₂) * (1-ξsc₂)/(1-ξsc₁)

also knowing that

Kp= psc₁/ps₁² = psc₂/ps₂²

psc₂/ps₂² = psc₁/ps₁² * (V₁/V₂) * (1-ξsc₂)/(1-ξsc₁)  /  [(V₁/V₂) * (ξsc₂/ξsc₁) ]² =

1 =  (V₂/V₁)(1-ξsc₂)*ξsc₁/ [(1-ξsc₁)*ξsc₂]

replacing ξsc₁= 1/11

1 =  (V₂/V₁)(1-ξsc₂)/ξsc₂ *(1/10)

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since V₁/V₂=2

ξsc₂ = 1/(10*2+1) = 1/21

therefore the decrease in moles of Sulfuryl chloride is

Δnsc/nsc₁ = (ξsc₂-ξsc₁)/(1-ξsc₁) =  (1/21-1/11)/(10/11)= (11/21-1)/10 = -1/21 (-4.76%)

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