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gulaghasi [49]
3 years ago
10

A 20.0 g piece of a metal is heated and place into a calorimeter containing 250.0 g of water initially at 25.0 oC. The final tem

perature of the water is 31.5 oC. What is the heat change of the metal in joules? The specific heat of water is 4.184 J/goC
Chemistry
2 answers:
tatiyna3 years ago
7 0

Answer:

Heat change of the metal = -6799 J

Explanation:

Step 1: Data given

Mass of the metal = 20.0 grams

Mass of water = 250.0 grams

Initial temperature of water = 25.0 °C

Final temperature of water = 31.5 °C

Step 2: Calculate the heat change of the metal in joules?

Heat lost =  heat gained

Qlost = -Qgained

Q = m*C*ΔT

m(metal) * C(metal) * ΔT(metal) = -m(water) * C(water) * ΔT(water)

⇒with m(metal) = the mass of metal = 20.0 grams

⇒with C(metal) = the specific heat of meteal = ?

⇒with ΔT(metal) = the change of temperature of the metal = ?

⇒with m(water) = the mass of water = 250.0 grams

⇒with C(water) = the specific heat of water = 4.184 J/g°C

⇒with ΔT(water) = the change of temperature of water = T2 - T1 = 31.5 °C - 25.0 °C = 6.5 °C

The heat change of metal = heat change of water

Q = 250 * 4.184 * 6.5

Q = 6799 J

Heat change of water = 6799 J

Heat change of the metal = -6799 J

BartSMP [9]3 years ago
6 0

Answer:

Q_{metal} = -6799\,J

Explanation:

By the First Law of Thermodynamics, the piece of metal and water reaches thermal equilibrium when water receives heat from the piece of metal. Then:

Q_{metal} = - Q_{w}

Q_{metal} = m_{w} \cdot c_{p,w}\cdot (T_{1}-T_{2})

Q_{metal} = (250\,g)\cdot \left(4.184\,\frac{J}{g\cdot ^{\textdegree}C} \right)\cdot (25\,^{\textdegree}C - 31.5\,^{\textdegree}C)

Q_{metal} = -6799\,J

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When a 3.25 g sample of solid sodium hydroxide was dissolved in a calorimeter in 100.0 g of water, the temperature rose from 23.
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Answer : The enthalpy change for the solution is 42.8 kJ/mol

Explanation :

Heat released by the reaction = Heat absorbed by the calorimeter + Heat absorbed by the water

q=[q_1+q_2]

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where,

q = heat released by the reaction

q_1 = heat absorbed by the calorimeter

q_2 = heat absorbed by the water

c_1 = specific heat of calorimeter = 15.8J/^oC

c_2 = specific heat of water = 4.18J/g^oC

m = mass of water = 100.0 g

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Now put all the given values in the above formula, we get:

q=[(15.8J/^oC\times 8.1^oC)+(100.0g\times 4.18J/g^oC\times 8.1^oC)]

q=3513.8J=3.5138kJ        (1 kJ = 1000 J)

Now we have to calculate the enthalpy change for the solution.

\Delta H=\frac{q}{n}

where,

\Delta H = enthalpy change = ?

q = heat released = 3.5138 kJ

m = mass of NaOH = 3.25 g

Molar mass of NaOH = 40 g/mole

\text{Moles of }NaOH=\frac{\text{Mass of }NaOH}{\text{Molar mass of }NaOH}=\frac{3.25g}{40g/mole}=0.0812mole

Now,

\Delta H=\frac{3.5138kJ}{0.0821mole}=42.8kJ/mol

Therefore, the enthalpy change for the solution is 42.8 kJ/mol

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