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Bond [772]
2 years ago
9

The irreversible elementary gas-phase reaction is carried out isothermally at 305 K in a packed-bed reactor with 100 kg of catal

yst. The entering pressure was 20 atm and the exit pressure is 2 atm. The feed is equal molar in A and B and the flow is in the turbulent flow regime, with FA0 10 mol/min and CA0 0.4 mol/dm3. Currently 80% conversion is achieved. What would be the conversion
Chemistry
1 answer:
tamaranim1 [39]2 years ago
5 0

Answer:

0.856.

Explanation:

Lets represent the irreversible elementary gas phase equation of reaction as

A + B -----------------------------------> C + D

We have that the percentage of conversion is 80%.

The pressure, p from the ratio of exit pressure and entering pressure is p = 2/20 = 1/10 = 0.1.

Therefore, n = 1 - p^2/ weight of the catalyst = 1 - 0.1^2/ 100 = 9.9 × 10^-3 kg cat^-.

Now, let's make use of the equation below;

J/ 1 - J = kb^2/ u [ w - nw^2/2] ----------(1).

0.8 / 1- 0.8 = k ( 0.4)^2/ 10 [ 100 - (9.9× 10^-3 × 100^2/ 2] .

k = 4.95 dm^6/ kg.cat .mol.min

The turbulent flow= 1/2 × 9.9 × 10^-3 = 4.95 × 10^-3 kg cat^-.

Thus, making use of the equation (1) again, we have that;

{4.95 × 10^-3 × 0.4}/ 10 × [ 100 - (4.95 × 10^-3 × 100^2)] / 2 = 5.964.

Therefore, a/1 - a = 5.964.

5.964( 1 - a) = a.

5.964 - 5.964a = a.

5.964 = a + 5.964a.

5.964 = 6.964a.

a = 5.964/ 6.964 = 0.856.

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7 0
2 years ago
0.53g of acetanilide was subjected to kjeldahl determination and the ammonia produced was collected in 50cm3 of 0.50M of h2so4.o
Lady bird [3.3K]

Answer:

10.57% of N in acetanilide

Explanation:

All nitrogen in the sample is converted in NH₃ in the Kjeldahl determination. The NH₃ reacts with H₂SO₄ as follows:

2NH₃ + H₂SO₄ → 2NH₄⁺ + SO₄²⁻

The acid in excess in titrated with Na₂CO₃ as follows:

Na₂CO₃ + H₂SO₄ → Na₂SO₄ + H₂O + CO₂

To solve this question we must find the moles of sodium carbonate = Moles of H₂SO₄ in excess. The added moles - Moles in excess = Moles of sulfuric acid that reacts:

<em>Moles Na₂CO₃ anf Moles H₂SO₄ in excess:</em>

0.025L * (0.05mol / L) = 1.25x10⁻³ moles Na₂CO₃ / 0.01360L =

0.09191M * 0.250L = 0.0230 moles H₂SO₄ in excess.

<em>Moles H₂SO₄ added:</em>

0.050L * (0.50mol / L) = 0.0250 moles H₂SO₄ added

<em>Moles that react:</em>

0.0250 moles - 0.0230 moles = 0.0020 moles H₂SO₄

<em>Moles of NH₃ = Moles N:</em>

0.0020 moles H₂SO₄ * (2mol NH₃ / 1mol H₂SO₄) = 0.0040 moles NH₃ = Moles N

<em>mass N and mass percent:</em>

0.0040 moles N * (14g / mol) = 0.056gN / 0.53g * 100 =

<h3>10.57% of N in acetanilide</h3>
7 0
2 years ago
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