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ddd [48]
3 years ago
10

Draw all four products obtained when 2-ethyl-3-methyl-1,3-cyclohexadiene is treated with HBr at room temperature and show the me

chanism of their formation. For the mechanism, include lone pairs and charges in your answer. Do not draw out any hydrogen explicitly. Do not use abbreviations such as Me or Ph.
Chemistry
1 answer:
LenKa [72]3 years ago
5 0

Answer:

See explanation below

Explanation:

In this case we have reaction of addition. In this case a diene reacting with an acid as HBr. This reaction is known as Hydrohalogenation, and, as we have a diene, this kind of reaction can be done as 1,4 addition. Which means that the reaction will be undergoing with an adition in the carbon 1, and carbon 4.

At room temperature we can expect that this reaction can be done in thermodynamic conditions, Now, as the problem states that is forming 4 products, we can expect products of a 1,2 addition too. This product can be formed if the reaction is taking place in the most stable carbocation, and then, by resonance, we can expect the 1,4 product too.

Now, the HBr can be attacked by the double bond of the first position, giving two possible products or by the double bond of the third position giving the other two products. These products are all possible, obviously the most stable will be the major of all of them, but the other three are perfectly possible. One product is formed without doing much, and the other by resonance. Same happens with the other double bond.

In the picture below, you have the mechanism for all the 4 products.

Hope this helps

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How many grams of ammonia must you start with to make 900.00 l of a 0.140 m aqueous solution of nitric acid? assume all the reac
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You need the set of reactions that goes from ammonia to nitric acid.
<span>
1) 4NH3(g)+5O2(g)-->4NO(g)+6H2O(g)

2) 2NO(g)+O2(g)-->2NO2(g)

3) 3NO2(g)+H2O(l)-->2HNO3(aq)+NO(g)

State the ratio of moles of HNO3 to NH3:

4 moles of NH3 produce 4 mole of NO,

4 moles of NO produce 4 moles of NO2

4 moles of NO2 produce 4 * (2 / 3) moles of HNO3 = 8/3 moles of HNO3.

=> (8/3) moles HNO3 : 4 moles NH3

Calculate the number of moles of HNO3 in 900.00 l of 0.140 M solution

M = n / V => n = M * V = 0.140 M * 900.00 liter = 126 moles HNO3

Use proportions:

(</span><span>8/3) moles HNO3 / 4 moles NH3 = 126 moles HNO3 / x

=> x = 126 moles HNO3 * 4 moles NH3 / (8/3 moles HNO3) = 189 moles NH3

Convert moles to grams:

molar mass NH3 = 14 g/mol + 3 * 1g/mol = 17 g/mol

mass in grams = number of moles * molar mass = 189 moles * 17 g/mol = 3213 g

Answer: 3213 g.
</span>
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3 years ago
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